# US 10,770,753 B2 · Electrolyte for fluoride ion battery and fluoride ion battery

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- Number: US 10,770,753 B2
- Document ID: US10770753B2
- Status: Granted
- Kind: B2
- Application number: 15/071,678
- Filed: 2016-03-16
- Published: 2016-10-06
- Granted: 2020-09-08
- Earliest claimed: 2015-04-03
- Assignees: Toyota Jidosha Kabushiki Kaisha; Kyoto University
- Applicants: Toyota Jidosha Kabushiki Kaisha; Kyoto University
- Inventors: Hirofumi Nakamoto; Zempachi Ogumi; Takeshi Abe
- Web page: https://patentgrep.com/patent/US10770753B2

## CPC

- H01M 10/0568: characterised by the solutes
- H01M 10/05: Accumulators with non-aqueous electrolyte (H01M10/39 takes precedence)
- H01M 2300/0025: Organic electrolyte
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

The object of the present invention is to provide an electrolyte for a fluoride ion battery with high activity for fluoridating an active material. The present invention solves the problem by providing an electrolyte for a fluoride ion battery comprising a fluoride complex salt as at least one of LiPF6 and LiBF4, and an organic solvent; and B/A is 0.125 or more in the case where a substance amount of the organic solvent is regarded as A (mol) and a substance amount of the fluoride complex salt is regarded as B (mol).

## Claims

### Claim 1

A fluoride ion battery comprising a cathode active material layer, an anode active material layer, and an electrolyte layer formed between the cathode active material layer and the anode active material layer, wherein
the cathode active material layer includes a cathode active material comprising at least one kind of metal simple substance, alloy, metal oxide, carbon material, and fluorides thereof, and the cathode active material is an active material that is defluoridated during discharge,
the anode active material layer includes an anode active material comprising at least one kind of metal simple substance, alloy, metal oxide, and fluorides thereof, and the anode active material is an active material that is fluoridated during discharge,
the electrolyte layer includes an electrolyte containing a fluoride complex salt as at least one of LiPF6 and LiBF4, and one or more organic solvents, and the electrolyte layer does not contain a fluoride salt having a fluoride ion as an anion component, and
B/A is 0.125 or more and 1 or less in the case when a total amount of all organic solvents in the electrolyte layer is regarded as A (mol) and a total amount of all the fluoride complex salt in the electrolyte layer is regarded as B (mol).