# US 10,770,608 B2 · Semi-transparent thin-film photovoltaic mono cell

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- Number: US 10,770,608 B2
- Document ID: US10770608B2
- Status: Granted
- Kind: B2
- Application number: 14/893,024
- Filed: 2014-05-22
- Published: 2016-05-05
- Granted: 2020-09-08
- Earliest claimed: 2013-05-23
- Assignees: Garmin Switzerland GmbH
- Applicants: Garmin Switzerland GmbH
- Inventors: Philippe Gilbert Frederic Cardi; Sylvain De Vecchi
- Web page: https://patentgrep.com/patent/US10770608B2

## CPC

- H10F 19/33: Patterning processes to connect the photovoltaic cells, e.g. laser cutting of conductive or active layers
- H10F 19/35: Structures for the connecting of adjacent photovoltaic cells, e.g. interconnections or insulating spacers
- H10F 19/37: comprising means for obtaining partial light transmission through the integrated devices, or the assemblies of multiple devices, e.g. partially transparent thin-film photovoltaic modules for windows
- H10F 77/211: {for photovoltaic cells}
- H10K 30/83: comprising arrangements for extracting the current from the cell, e.g. metal finger grid systems to reduce the serial resistance of transparent electrodes
- H10F 71/1385: {Etching transparent electrodes}
- H10K 77/111: {Flexible substrates}
- Y02E 10/549: Organic PV cells
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- H10F: INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

The invention relates to a photovoltaic mono cell that is semi-transparent to light, comprising a plurality of active photovoltaic zones that are separated by transparent zones, said active photovoltaic zones being formed from a stack of thin films arranged on a substrate that is transparent to light, said stack of thin films consisting at least of a transparent electrode, an absorber layer and a metal electrode, said transparent zones being apertures produced at least in the metal electrode and in the absorber layer in order to allow as much light as possible to pass, characterized in that it furthermore comprises an electrically conductive collecting gate arranged either making contact with the front electrode in order to decrease the electrical resistance of the transparent electrode, or making contact with the absorber in order to facilitate collection of the electrical current generated by said mono cell.

## Claims

### Claim 1

A photovoltaic mono cell semi-transparent to light, comprising:
a plurality of photovoltaic active zones separated by transparency zones,
said photovoltaic active zones being formed of a stack of thin films comprising a transparent electrode, an absorber film and a metallic electrode which are arranged in the stated order, from a first side of the stack to a second side of the stack, on a substrate transparent to light, such that the first side of the stack is closest to the substrate;
and said transparency zones being apertures made at least in the metallic electrode and in the absorber film to allow through light;
an electrically conducting collection gate arranged in contact with the transparent electrode to reduce its electrical resistance and avoid direct physical or electrical contact with the metallic electrode,
a first collection bus linked to the collection gate to collect electrical charges from the transparent electrode; and
a second collection bus linked to the metallic electrode, the second collection bus spaced apart from the first collection bus,
wherein said photovoltaic active zones furthermore contain several channels, made in the metallic electrode and the absorber film, said collection gate being separated from the metallic electrode and from the absorber film by a dielectric material, so as to reduce the series resistance of the transparent electrode while minimizing the visibility of the collection gate,
wherein the collection gate substantially covers the photovoltaic active zones.

### Claim 2 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein apertures are in the form of discontinuous or non-discontinuous rectilinear bands, or according to any other shapes, said collection gate being adapted to said apertures so as to limit visibility of said collection gate.

### Claim 3 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein the absorber films and the metallic electrodes are less wide than the transparent electrodes, and the collection gate comprises fine metallic strips arranged on the transparent electrode and situated aligned with the absorber film.

### Claim 4 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein said collection gate is metallic.

### Claim 5 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein said dielectric material is transparent or semi-transparent to visible light.

### Claim 6 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein the refractive index of the dielectric material lies between the refractive index of the transparent substrate or of the transparent electrode and that of the air.

### Claim 7 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein the refractive index of the dielectric material lies between the refractive index of the transparent substrate or of the transparent electrode and that of a transparent optical glue which forms part of the photovoltaic mono cell.

### Claim 8 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein said photovoltaic active zones or the transparency zones are organized into arrays of linear, circular or polygonal elementary geometric structures.

### Claim 9 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein said transparent electrode comprises graphene or metallic nanostructures or a transparent conducting oxide such as SnO2, ITO, IZO, AZO, BZO, GZO or ZnO.

### Claim 10 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein said absorber film comprises one or more inorganic and/or organic semi-conducting materials, based on amorphous or microcrystalline silicon, GaAs (gallium arsenide), CdTe (cadmium telluride), CIGS (copper-indium-gallium-selenium) or based on polymers.

### Claim 11 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein said metallic electrode comprises a metal such as aluminum (Al), nickel (Ni), gold (Au), silver (Ag), copper (Cu), molybdenum (Mo), chromium (Cr), titanium (Ti) or palladium (Pd).

### Claim 12 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein the transparent substrate comprises a solid material made of mineral glass, organic glass or else a polymer of PMMA, PET or polycarbonate type.

### Claim 13 (depends on 1)

The photovoltaic mono cell as claimed in claim 1, wherein the transparent substrate is covered with an antireflection or anti-UV functional surface.

### Claim 14

A photovoltaic mono cell semi-transparent to light, comprising:
a plurality of photovoltaic active zones separated by transparency zones,
said photovoltaic active zones being formed of a stack of thin films comprising a transparent electrode, an absorber film and a metallic electrode which are arranged in the stated order, from a first side of the stack to a second side of the stack, on a substrate transparent to light, such that the first side of the stack is closest to the substrate and the transparent electrode is in contact with the substrate;
and said transparency zones being apertures made at least in the metallic electrode and in the absorber film to allow through light;
an electrically conducting collection gate arranged to avoid direct physical or electrical contact with the metallic electrode and positioned either in contact with the transparent electrode to reduce its electrical resistance, or in contact with the absorber to facilitate the collection of electric current generated by said mono cell,
a first collection bus linked to the collection gate to collect electrical charges from the transparent electrode; and
a second collection bus linked to the metallic electrode, the second collection bus spaced apart from the first collection bus,
wherein the collection gate substantially covers the photovoltaic active zones.
