# US 10,768,524 B2 · Photomask blank substrate container, method for storing photomask blank substrate and method for transporting photomask blank substrate

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- Number: US 10,768,524 B2
- Document ID: US10768524B2
- Status: Granted
- Kind: B2
- Application number: 15/477,599
- Filed: 2017-04-03
- Published: 2017-10-12
- Granted: 2020-09-08
- Earliest claimed: 2016-04-07
- Assignees: Shin-Etsu Chemical Co., Ltd.
- Applicants: Shin-Etsu Chemical Co., Ltd.
- Inventors: Shogo Ito; Ryuji Koitabashi
- Web page: https://patentgrep.com/patent/US10768524B2

## CPC

- G03F 1/66: Containers specially adapted for masks, mask blanks or pellicles; Preparation thereof
- G03F 1/60: Substrates
- H10P 72/1906: {specially adapted for containing masks, reticles or pellicles}
- H10P 72/1916: {characterised by sealing arrangements}
- H10P 72/1926: {characterised by the presence of atmosphere modifying elements inside or attached to the closed carrier}
- G03F 7/70975: {Assembly, maintenance, transport or storage of apparatus}
- G03F: PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR; (phototypographic composing devices B41B; photosensitive materials or processes for photographic purposes G03C; electrophotography, sensitive layers or processes therefor G03G)
- H10P: GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10

## Abstract

A photomask blank substrate container having an inner member, inner cassette and retainer member, container main body having a lower box and an upper lid, and a sealing tape, in which the container main body and inner member include a polymer-based material in which when 0.1 g of a sample thereof is retained at 40° C. for 60 minutes to release an outgas component, the outgas total amount detected by a gas chromatography mass spectrometer is 1.9×103 ng or less in terms of n-tetradecane, and the sealing tape is a material in which when a size of 10 mm×10 mm of a sample thereof is retained at 150° C. for 10 minutes to release an outgas component, the outgas total amount detected by a gas chromatography mass spectrometer is 1.8×103 ng or less in terms of n-tetradecane. This photomask blank substrate container allows storing and transporting the photomask blank substrate while suppressing influence on the resist pattern.

## Claims

### Claim 1

A photomask blank substrate container for containing a photomask blank substrate, comprising
an inner member having an inner cassette capable of containing the photomask blank substrate, and a retainer member for fixing the photomask blank substrate contained in the inner cassette from above,
a container main body having a lower box capable of containing the inner cassette, and an upper lid capable of engaging with the retainer member to an inside, and
a sealing tape for sealing the container main body,
the lower box engaging with the upper lid directly,
wherein the container main body and the inner member comprise a polymer-based material in which when 0.1 g of a sample thereof is retained at 40° C. for 60 minutes to release an outgas component, a total amount of the outgas detected by a gas chromatography mass spectrometer is 500 ng or less in terms of n-tetradecane,
the sealing tape is a material in which when a size of 10 mm×10 mm of a sample thereof is retained at 150° C. for 10 minutes to release an outgas component, a total amount of the outgas detected by a gas chromatography mass spectrometer is 1.0×103 ng or less in terms of n-tetradecane,
the photomask blank substrate is a material onto which a chemical amplification type resist has been coated, wherein
the container main body comprises a polymer-based material containing a polycarbonate as a main component, and a surface resistance value thereof is 2.0×104 Ω/sq or less, and
the sealing tape has: (i) a substrate comprising a polymer selected from the group consisting of polyethylene terephthalate, polypropylene and polyethylene, and (ii) an adhesive surface comprising polyacrylic ester.

### Claim 2 (depends on 1)

The photomask blank substrate container according to claim 1, wherein the inner member comprises a polymer-based material in which when 2 g of a sample thereof is retained at 100° C. for 20 minutes to release an outgas component, the total amount of the outgas detected by a gas chromatography mass spectrometer is 1.0×103 ng or less in terms of n-tetradecane.

### Claim 3 (depends on 1)

The photomask blank substrate container according to claim 1, wherein
a sum of a total amount of outgas by outgas component generated from an inner surface of the container main body, and a total amount of outgas by outgas component generated from a surface of the inner member is less than 3.0×103 μg, and
a total amount of outgas by outgas component generated from the sealing tape sealing the container main body is less than 1.4×102 μg.

### Claim 4 (depends on 2)

The photomask blank substrate container according to claim 2, wherein
a sum of a total amount of outgas by outgas component generated from an inner surface of the container main body, and a total amount of outgas by outgas component generated from a surface of the inner member is less than 3.0×103 μg, and
a total amount of outgas by outgas component generated from the sealing tape sealing the container main body is less than 1.4×102 μg.

### Claim 5 (depends on 1)

A method of storing a photomask blank substrate which comprises storing the photomask blank substrate with the photomask blank substrate contained in the photomask blank substrate container according to claim 1.

### Claim 6 (depends on 1)

A method of transporting a photomask blank substrate which comprises transporting the photomask blank substrate with the photomask blank substrate contained in the photomask blank substrate container according to claim 1.
