# US 10,768,314 B2 · Optical element

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- Number: US 10,768,314 B2
- Document ID: US10768314B2
- Status: Granted
- Kind: B2
- Application number: 15/735,275
- Filed: 2016-06-10
- Published: 2018-05-03
- Granted: 2020-09-08
- Earliest claimed: 2015-06-11
- Applicants: IQ Structures S.R.O.; Crytur SOPL. S.R.O.
- Inventors: Roman Houha; Tomas Tethal; Zbynek Ryzi; Jan Kubat; Tomas Fidler
- Web page: https://patentgrep.com/patent/US10768314B2

## CPC

- G01T 1/2002: {Optical details, e.g. reflecting or diffusing layers}
- F21K 9/64: using wavelength conversion means distinct or spaced from the light-generating element, e.g. a remote phosphor layer
- G01T 1/202: the detector being a crystal
- H10F 39/1898: {Indirect radiation image sensors, e.g. using luminescent members}
- H10H 20/8514: {characterised by their shape, e.g. plate or foil}
- G01T: MEASUREMENT OF NUCLEAR OR X-RADIATION (radiation analysis of materials, mass spectrometry G01N23/00; tubes for determining the presence, intensity, density or energy of radiation or particles H01J47/00)
- F21K: NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
- H10F: INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10H: INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS

## Abstract

An optical element (1) comprises: a body (2) of radiation converting monocrystalline material, e.g. of a luminescent or scintillator material, and an extraction structure (4, 6) applied to at least one output or input surface of the body (2); wherein the extraction structure (4, 6) is constructed and configured such that radiation at an output (19) of the body (2) is directionally modified, especially in terms of energy or intensity or of directional distribution or of both, as compared with radiation at the output of the body (2) in the absence of said extraction structure (4, 6), by interaction of radiation entering and/or propagating within and/or exiting the body (2) with the said extraction structure (4, 6), e.g. such as to reduce or ameliorate the deleterious effects of TIR within the body (2).

## Claims

### Claim 1

An optical element comprising:
a body of radiation converting monocrystalline material, and
an extraction structure applied to at least one surface of the body of radiation converting monocrystalline material;
wherein the extraction structure is constructed and configured such that radiation at an output of the body of radiation converting monocrystalline material is directionally modified, as compared with radiation at the output of the body of radiation converting monocrystalline material in the absence of said extraction structure, by interaction of radiation selected from the group consisting of radiation entering the body, radiation propagating within the body and radiation exiting the body, of radiation converting monocrystalline material with the said extraction structure;
and wherein the extraction structure is configured such that, for at least one wavelength of the radiation at the output of the said body, the energy or intensity of the radiation at the output of the body of radiation converting monocrystalline material in at least one direction of propagation is increased, compared to the energy or intensity of the radiation at the output of the said body in the said direction in the absence of the said extraction structure.

### Claim 2 (depends on 1)

An optical element according to claim 1, wherein the extraction structure is configured such that it modifies one of the following (i)-(iii):
(i) the energy or intensity of the radiation at the output of the body of radiation converting monocrystalline material via interactions of radiation entering and/or propagating within and/or exiting the said body with the said surface,
(ii) the directional distribution of radiation selected from the group consisting of exiting, entering, and propagating within the body of radiation converting monocrystalline material via interactions with the said surface,
(iii) a combination of both (i) and (ii),
wherein in both cases (i) and (ii) the said directional modification is in comparison with radiation at the same output of the body but in the absence of the said extraction structure(s) applied thereto.

### Claim 3 (depends on 1)

An optical element according to claim 1, wherein the said output of the body of radiation converting monocrystalline material at which the directional modification of the radiation is defined is an output surface or an output region or portion of the said body.

### Claim 4 (depends on 1)

An optical element according to claim 1, wherein the at least one surface of the body of radiation converting monocrystalline material having an extraction structure applied thereto is selected from the group consisting of:
(i) a respective output surface of the body, whereby the extraction structure acts to directionally modify radiation selected from the group consisting of radiation exiting the body, propagating within the body, and interacting with the respective output surface;
(ii) a respective input surface of the body, whereby the extraction structure acts to directionally modify radiation selected from the group consisting of radiation entering the body, propagating within the body, and interacting with the respective input surface; and
(iii) a respective surface that is an other surface and such other surface is not an input surface and is not an output surface thereof, whereby the extraction structure acts to directionally modify radiation selected from the group consisting of radiation passing through the body, generating within the body, propagating within the body, and interacting with that other surface.

### Claim 5 (depends on 4)

An optical element according to claim 4, wherein (iii) is satisfied and wherein the said other surface is any side or lateral surface of the body.

### Claim 6 (depends on 1)

An optical element according to claim 1, wherein the radiation converting monocrystalline material comprises a material selected from the group consisting of a luminescent material and a scintillator material.

### Claim 7 (depends on 1)

An optical element according to claim 1, wherein the radiation converting monocrystalline material comprises a monocrystalline complex oxide with a composition according to the following general formula (I):
PxQyOz:R (I)
in which:
P is one or more elements selected from Gd, Lu, Tb, Y, Pb, Zn, Ca, Cd, Bi, La;
Q is one or more elements selected from Al, Ga, Si, Sc, W, Ge, B;
O is the element oxygen;
x and y are each independently a positive integral or non-integral number, and x is in the range 0<x≤3 and y is in the range 0<y≤5;
the ratio x/y is in the range from 0.44 to 2.55;
z is an integral or non-integral number in the range from 2.5 to 12.5;
R is at least one doping element selected from the group consisting of Ce, Pr, Nd, Yb, Sm, Eu, Dy, Mn, Mg, Zr, Cu, Cr, Ti; and
the content of R in the material is in the range from 0 to 20 mol %.

### Claim 8 (depends on 7)

An optical element according to claim 7, wherein the said complex oxide material is selected from any one of the structural groups represented by garnets, orthosilicates, perovskites and pyrosilicates, and wherein, in the compositional formula (I):
x is an integer selected from 1, 2 and 3;
y is an integer selected from 1, 4 and 5; and
z is an integer selected from 3, 4, 5 and 12;
wherein the aforementioned values of x, y and z are defined in the absence of any R, and if R is present then it replaces a proportion of at least one of the said defined amounts of P and Q present.

### Claim 9 (depends on 1)

An optical element according to claim 1, wherein the radiation converting monocrystalline material comprises a monocrystalline sesquioxide with a composition according to the following alternative general formula (II):
Ss-tOu:Tt (II)
in which:
S is one or more elements selected from Al, Lu, Gd Tb, La;
O is the element oxygen;
s is a number in the range from 0.9 to 2.5;
t is a number in the range from 0 to 1;
u is a number in the range from 2.8 to 3.2; and
T is at least one doping element selected from the group consisting of Ce, Eu, Pr, Yb, Nd, Er, Tm, Ti, Mn.

### Claim 10 (depends on 1)

An optical element according to claim 1, wherein the body of radiation converting monocrystalline material is in the form selected from the group consisting of a generally planar plate, a generally planar platelet, a generally planar sheet, a substantially planar plate, a substantially planar platelet, and a substantially planar sheet.

### Claim 11 (depends on 1)

An optical element according to claim 1, wherein the extraction structure is applied to at least one of the group consisting of one surface, face, and side of the body of radiation converting monocrystalline material, the said surface(s), face(s) or side(s) constituting one side of an interface of the body at which, in use, radiation would undergo total internal reflection (TIR) were it not to be for the presence of the extraction structure thereon.

### Claim 12 (depends on 1)

An optical element according to claim 1, wherein the extraction structure comprises at least one optical structure selected from the group consisting of a micro-structural, nano-structural and thin-film based optical structure applied to at least one of the group consisting of surface, face, and side of the body of radiation converting monocrystalline material with which radiation selected from the group consisting of exiting the body of radiation, entering the body of radiation and propagating within the body of radiation converting monocrystalline material interacts.

### Claim 13 (depends on 12)

An optical element according to claim 12, wherein the or each optical structure comprises one or more layers or sub-layers, each of which layers or sub-layers having optical properties and optical function(s) wherein the optical properties and optical functions comprise one or more optical properties and optical functions selected from the group consisting of: optical properties which are (i) the same as the optical properties of the other layers in the optical structure, (ii) the same as the optical properties of the other sublayers in the optical structure, (iii) different from the optical properties of the other layers in the optical structure, (iv) different from the optical properties of the other sublayers in the optical structure, (v) the same as the optical functions of the other layers in the optical structure, (vi) the same as the optical functions of the other sublayers in the optical structure, (vii) different from the optical functions of the other layers in the optical structure, and (viii) different from the optical functions of the other sublayers in the optical structure;
wherein the optical properties or optical functions of any one or more layers or sub-layers of the optical structure(s) which form(s) the extraction structure is/are selected from any one or more of the group consisting of the following:
a filter,
a semi-transparent mirror,
a reflective layer,
an anti- (or non-)reflective layer,
a refractive layer,
a diffractive layer,
an optical lens or an array of lenses or lenslets,
an interference structure, or a grating or interference filter,
an optical modulation layer, or a layer that modulates amplitude, phase or polarization of radiation incident thereon or passing therethrough,
a layer with a modulated, or locally modulated, refractive index or complex refractive index,
a surface relief layer,
a holographic layer.

### Claim 14 (depends on 13)

An optical element according to claim 13, wherein the one or more layers or sub-layers of the optical structure is/are formed from one or more materials selected from plastics materials, metals and metal alloys, dielectric materials, and any combination of any of the foregoing materials, and wherein the thickness of the one or more layers and sub-layers forming the or each optical structure is collectively from about 10 nm up to about 1 or 2 or 5 or 10 or 20 or 50 or 100 or 200 or 500 or 1000 micrometres.

### Claim 15 (depends on 1)

An optical element according to claim 1, wherein the body of radiation converting material is selected from the group consisting of a generally planar plate, a generally planar platelet and a generally planar sheet having a cuboidal three-dimensional shape, and at least one of its major faces has applied thereto one or more said extraction structure(s).

### Claim 16 (depends on 15)

An optical element according to claim 15, wherein either or both of the body's minor faces also have applied thereto at least one respective extraction structure.

### Claim 17 (depends on 1)

An optical element according to claim 1, wherein the extraction structure comprises an optical structure comprising a plurality of layers selected from the group consisting of layers and sub-layers, and wherein at least one of the said layers or sub-layers is constituted by being selected from the group consisting of a surface region, a portion and a layer of the said body of radiation converting monocrystalline material itself.

### Claim 18 (depends on 1)

A device comprising an optical element according to claim 1, wherein the device is selected from:
(i) an LED or LD device, and
(ii) an ionizing radiation detector device.

### Claim 19 (depends on 1)

A method of at least partially converting radiation incident on or passing through or generated within or propagated within an optical element, comprising:
providing an optical element according to claim 1; and
selected from the group consisting of applying onto the body of radiation converting monocrystalline material, passing through the body of radiation converting monocrystalline material, generating within the body of radiation converting monocrystalline material and propagating within the body of radiation converting monocrystalline material, radiation to be converted;
whereby radiation selected from the group consisting of exiting the body of radiation converting monocrystalline material, entering the body of radiation converting monocrystalline material, generated within the body of radiation converting monocrystalline material and propagated within the body of radiation converting monocrystalline material, is directionally modified via interaction(s) with the said extraction structure applied thereto,
and whereby for at least one wavelength of the radiation at the output of the said body, the energy or intensity of the radiation at the output of the body of radiation converting monocrystalline material in at least one direction of propagation is increased, compared to the energy or intensity of the radiation at the output of the said body in the said direction in the absence of the said extraction structure.

### Claim 20 (depends on 19)

A method according to claim 19, which is a method of directionally modifying radiation selected from the group consisting of exiting the body of radiation converting monocrystalline material, entering the body of radiation converting monocrystalline material and propagating within the body of radiation converting monocrystalline material, within an optical element comprising the body of radiation converting monocrystalline material, wherein the radiation selected from the group consisting of applied onto the body of radiation converting monocrystalline material, passed through the body of radiation converting monocrystalline material, generated within the body of radiation converting monocrystalline material and propagated within the body of radiation converting monocrystalline material, and at least partially converted by interaction(s) with the said body of radiation converting monocrystalline material.