# US 10,768,092 B2 · Measurement systems and methods for corrosion testing of coatings and materials

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- Number: US 10,768,092 B2
- Document ID: US10768092B2
- Status: Granted
- Kind: B2
- Application number: 14/496,164
- Filed: 2014-09-25
- Published: 2016-12-15
- Granted: 2020-09-08
- Earliest claimed: 2013-09-27
- Assignees: Luna Innovations Incorporated
- Applicants: Luna Innovations Incorporated
- Inventors: Fritz John Friedersdorf; Conrad Koenig Andrews; Paul Gordon Muskopf; Kathryn Beryl Ridder
- Web page: https://patentgrep.com/patent/US10768092B2

## CPC

- G01N 17/04: Corrosion probes
- G01N 3/02: Details
- G01N 3/06: Special adaptations of indicating or recording means
- G01N 17/02: Electrochemical measuring systems for weathering, corrosion or corrosion-protection measurement
- G01N 17/043: {Coupons}
- G01N 27/023: {where the material is placed in the field of a coil}
- G01N 27/041: {of a solid body}
- G01N 27/20: Investigating the presence of flaws
- G01N 27/22: by investigating capacitance
- G01N 33/0031: {comprising two or more sensors, e.g. a sensor array}
- G01N 3/08: by applying steady tensile or compressive forces (G01N3/28 takes precedence)
- G01N 3/20: by applying steady bending forces (G01N3/26, G01N3/28 take precedence)
- G01N 19/04: Measuring adhesive force between materials, e.g. of sealing tape, of coating
- G01N 2203/024: Corrosive
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

A measurement system permits environmental, corrosion damage, and mechanical property measurements to assess protection properties of coatings. The system includes one or more multi-sensor panels, each multi-sensor panel having sensors for assessing coating barrier properties, free corrosion, and galvanic corrosion. Each multi-sensor panel is installed on a test rack that contains electronics for sensor excitation and sensor data acquisition throughout a corrosion test. Sensor data is collected, stored, and communicated to a base station. A network of multiple test racks can be supported by a base station to compare the performance of different coatings and material combinations simultaneously. The test racks can be used in accelerated atmospheric corrosion tests, outdoor test sites, or application service environments. Measurements of the capacity of a coating to maintain barrier properties, prevent free corrosion, galvanic corrosion, and environment-assisted cracking can be used to develop, select, and predict service performance of coatings.

## Claims

### Claim 1

A system for measuring time varying processes of atmospheric corrosion, comprising:
a test rack holding a sensor panel including one or more sensors configured to measure, using an electrochemical process, one or more protective properties of a coating applied to the sensor panel, and
circuitry configured to obtain measurement information from the one or more sensors of the sensor panel and to evaluate the one or more protective properties of the coating,
wherein the test rack also holds one or more mechanical test assemblies, each mechanical test assembly having a mechanical test specimen, a load mechanism configured to apply a load to the mechanical test specimen, and a mechanical test specimen sensor configured to measure mechanical properties.

### Claim 2 (depends on 1)

The system in claim 1, wherein the load mechanism is configured to apply a load to the mechanical test specimen and the mechanical test specimen sensor is configured to measure environment-assisted crack growth rate in the mechanical test specimen during atmospheric corrosion testing.

### Claim 3 (depends on 1)

The system in claim 1, further comprising multiple test racks, wherein the circuitry is configured to obtain measurement information from each of the multiple test racks and to evaluate the sensors on each rack for susceptibility to corrosion based on the obtained measurement information.

### Claim 4 (depends on 3)

The system in claim 3, wherein the multiple test racks hold multiple sensor panels each including one or more sensors configured to measure one or more protective properties of a coating applied to the sensor panels of each test rack, and wherein different coatings are applied to sensor panels of different test racks, and wherein the circuitry is configured to obtain measurement information from the one or more sensors on each of the multiple sensor panels and multiple test racks to evaluate the one or more protective properties of each of the different coatings.

### Claim 5 (depends on 1)

The system in claim 1, further comprising communication circuitry configured to communicate measurement information or corrosion susceptibility evaluation information to a base station.

### Claim 6 (depends on 5)

The system in claim 5, wherein the communication circuitry includes radio communication circuitry configured to wirelessly communicate measurement information or corrosion susceptibility evaluation information to the base station.

### Claim 7 (depends on 1)

The system in claim 1, wherein the test rack holds multiple sensor panels each including one or more sensors configured to measure one or more protective properties of a different coating applied to different ones of the sensor panels, and wherein the circuitry is configured to obtain measurement information from the one or more sensors on each of the multiple sensor panels and to evaluate the one or more protective properties of each of the different coatings.

### Claim 8 (depends on 1)

The system in claim 1, wherein the sensor panel is removable from the test rack and the test rack is configured to receive another sensor panel when the sensor panel is removed from the test rack.

### Claim 9 (depends on 3)

The system in claim 3, wherein each of the multiple sensor panels is removable from the test rack, and wherein the test rack is configured to receive another sensor panel when one of the multiple sensor panels is removed from the test rack.

### Claim 10 (depends on 1)

The system in claim 1, wherein the sensor panel is disposable after a test of the coating.

### Claim 11 (depends on 1)

The system in claim 1, wherein the one or more protective properties indicate an effectiveness of the coating in preventing corrosion that attacks an underlying substrate upon which the coating is provided.

### Claim 12 (depends on 1)

The system in claim 1, wherein the one or more protective properties include one or more of: a barrier property of the coating, a protection of an underlying substrate upon which the coating is provided from free corrosion, or a protection of the substrate from galvanic corrosion.

### Claim 13 (depends on 1)

The system in claim 1, wherein the system is configured to obtain atmospheric corrosion information from a laboratory test chamber, an outdoor exposure site, or an application service location.

### Claim 14 (depends on 1)

The system in claim 1, wherein the sensor panel is a multi-sensor panel that includes a free corrosion sensor, a galvanic corrosion sensor, and a coating barrier property sensor.

### Claim 15 (depends on 1)

The system in claim 1, wherein the test rack also holds a standard coating test panel.

### Claim 16 (depends on 1)

The system in claim 1, wherein the test rack also holds one or more environmental sensors configured to provide environmental sensor information including one or more of measured relative humidity, air temperature, surface temperature, and conductivity parameters.

### Claim 17 (depends on 1)

The system in claim 1, wherein the test rack also holds one or more environmental sensors configured to provide environmental sensor information based on measured anions, cations, or gases and/or measured visible, infrared, or ultraviolet radiation.
