# US 10,767,261 B2 · Device and method for vacuum coating

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- Number: US 10,767,261 B2
- Document ID: US10767261B2
- Status: Granted
- Kind: B2
- Application number: 13/811,222
- Filed: 2011-07-22
- Published: 2013-11-28
- Granted: 2020-09-08
- Earliest claimed: 2010-07-23
- Assignees: Leybold Optics GmbH
- Applicants: Torsten Schmauder; Gunter Kern
- Inventors: Torsten Schmauder; Gunter Kern
- Web page: https://patentgrep.com/patent/US10767261B2

## CPC

- C23C 16/448: characterised by the method used for generating reactive gas streams, e.g. by evaporation or sublimation of precursor materials
- C23C 14/50: Substrate holders
- C23C 16/50: using electric discharges {(generation and control of plasma in discharge tubes for surface treatment H01J37/32, H01J37/34)}
- C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04)

## Abstract

The invention relates to a device for vacuum coating substrates in a vacuum chamber, comprising an elongated evaporator array having a plurality of evaporator elements arranged along a longitudinal axis and a first substrate carrier unit which is associated with the evaporator array and has a first pylon that can be rotated about a first axis and contains retaining means for substrates, wherein an angular offset of less than 10° is present between the longitudinal axis and the first rotational axis. The device is characterised in that at least one second substrate carrier unit is provided, which is associated with the evaporator array and has a second pylon that can be rotated about a second axis and contains retaining means for substrates, wherein an angular offset of less than 10° is present between the longitudinal axis and the second rotational axis. At least one second substrate carrier unit (22, 122, 222) which is associated with the evaporator array (10, 110, 110a) and has a second pylon that can be rotated about a second rotational axis (42, 242) and contains retaining means for substrates is provided, wherein the axes of the pylons are designed to be fixed relative to the longitudinal axis (40) of the evaporator array, an angular offset of less than 10° is present between the longitudinal axis (40) and second rotational axis (42, 242), and a geometric configuration of the evaporator array (10, 110, 110a) and of the first (21, 121, 221) and the at least second substrate carrier units (22, 122, 222) is provided such that substrates of the first (21, 121, 221) and the at least second substrate carrier units (22, 122, 222) can be coated with the same quality by means of the evaporator array (10). The invention further relates to a method for vacuum coating by means of the device.

## Claims

### Claim 1

A device for the vacuum coating of substrates in a vacuum chamber, comprising:
an elongate evaporator array having a number of metallic evaporator elements extending between carrier rods, wherein the evaporator elements are arranged along a vertical longitudinal axis with respect to one another and are configured to generate a vapor of a coating material;
a plurality of substrate carrier units associated with the evaporator array, comprising:
a first substrate carrier unit having a first columnar framework structure that can be rotated about a first rotation axis, wherein there is an angular offset of less than 10° between the longitudinal axis and the first rotation axis; and
a second substrate carrier unit having a second columnar framework structure that can be rotated about a second rotation axis, wherein there is an angular offset of less than 10° between the longitudinal axis and the second rotation axis,
wherein, when the first substrate carrier unit rotates about the first rotation axis and the second substrate carrier unit rotates about the second rotation axis, the axes of the columnar framework structures are stationary relative to the longitudinal axis of the evaporator array and the evaporator array generates the vapor of the coating material,
wherein the evaporator array does not rotate about its longitudinal axis,
wherein the first substrate carrier unit and the second substrate carrier unit do not rotate about the evaporator array,
wherein each of the plurality of substrate carrier units is arranged at geometrically equivalent positions relative to the evaporator array that take into account the spatial emissions characteristics of the individual evaporator elements and of the evaporator array as a whole such that coating can be carried out by the evaporator array on substrates with equal quality; and
wherein the spatial emission characteristic of an evaporator element is an angular dependence of a flow density of evaporated material of that evaporator element, and wherein the angle between the evaporator array and each substrate carrier unit is equivalent.

### Claim 2 (depends on 1)

The device as claimed in claim 1, wherein the evaporator elements have a horizontal longitudinal extent and a mirror-symmetrical emission characteristic with respect to a plane spanned by the horizontal longitudinal extent and the longitudinal axis.

### Claim 3 (depends on 1)

The device as claimed in claim 1, further comprising at least one treatment source associated with the first substrate carrier unit or the second substrate carrier unit.

### Claim 4 (depends on 3)

The device of claim 3, wherein the at least one treatment source is formed as a plasma source having at least one electrode pair.

### Claim 5 (depends on 3)

The device as claimed in claim 3, wherein the vacuum chamber comprises:
a first sub-chamber having an opening in the wall of the vacuum chamber,
at least one second sub-chamber associated with the first sub-chamber, wherein the at least one second sub-chamber can be positioned to close the first sub-chamber in a vacuum-tight fashion, wherein the evaporator array, the first substrate carrier unit, and the second substrate carrier unit, and the at least one treatment source are accommodated in the at least one second sub-chamber.

### Claim 6 (depends on 5)

The device as claimed in claim 5, wherein the second sub-chamber can be positioned relative to the first sub-chamber by swiveling the second sub-chamber about a swivel axis.

### Claim 7 (depends on 5)

The device as claimed in claim 5, wherein the vacuum chamber comprises a further sub-chamber associated with the first sub-chamber, wherein the further sub-chamber can be positioned to close the first sub-chamber in a vacuum-tight fashion.

### Claim 8 (depends on 5)

The device as claimed in claim 5, further comprising at least one treatment source associated with the first substrate carrier unit or the second substrate carrier unit, wherein the at least one treatment source is formed as a plasma source having at least one electrode pair.

### Claim 9 (depends on 8)

The device as claimed in claim 8, wherein at least one electrode of the at least one electrode pair is arranged in the first sub-chamber and at least one associated back electrode of the at least one electrode pair is arranged in the second sub-chamber, wherein the back electrode can be positioned together with the second sub-chamber relative to the first sub-chamber.

### Claim 10 (depends on 8)

The device as claimed in claim 8, wherein the at least one electrode pair comprises at least one electrode in the form of a plate.

### Claim 11 (depends on 1)

The device as claimed in claim 1, further comprising at least one treatment source associated with at least one of the first substrate carrier unit and the second substrate carrier unit, wherein the dimensioning of at least one of the evaporator array and the treatment sources comprises an extension of at least one of the evaporator array and the treatment sources beyond the end regions of the substrate carrier units in order to compensate for spatial end effects.

### Claim 12 (depends on 1)

The device as claimed in claim 1, wherein a distance of the evaporator elements from one another can be adjusted in order to compensate for a decrease in a coating rate in the end regions of the evaporator array or of the substrate carrier units.

### Claim 13

A device for the vacuum coating of substrates in a vacuum chamber, comprising:
an elongate evaporator array having a number of metallic evaporator elements extending between carrier rods, wherein the metallic evaporator elements are arranged along a vertical longitudinal axis with respect to one another and are configured to generate a vapor of a coating material;
a plurality of substrate carrier units associated with the evaporator array, comprising:
a first substrate carrier unit having a first cylindrical pylon that can be rotated about a first rotation axis and being configured to retain a first substrate on the curved portion of the first pylon surface, wherein there is an angular offset of less than 10° between the longitudinal axis and the first rotation axis; and
a second substrate carrier unit having a second cylindrical pylon that can be rotated about a second rotation axis and being configured to retain a second substrate on the curved portion of the second pylon surface, wherein there is an angular offset of less than 10° between the longitudinal axis and the second rotation axis,
wherein, when the first substrate carrier unit rotates about the first rotation axis and the second substrate carrier unit rotates about the second rotation axis, the axes of the pylons are stationary relative to the longitudinal axis of the evaporator array and the evaporator array generates the vapor of the coating material,
wherein the evaporator array does not rotate about its longitudinal axis, the first substrate carrier unit and the second substrate carrier unit do not rotate about the evaporator array,
wherein a first substrate retained by the first substrate carrier unit rotates in an off-center position to the first rotation axis and a second substrate retained by the second substrate carrier unit rotates in an off-center position to the second rotation axis, and
wherein each of the plurality of substrate carrier units is arranged at geometrically equivalent positions relative to the evaporator array that take into account the spatial emissions characteristics of the individual metallic evaporator elements and of the evaporator array as a whole such that coating can be carried out by the evaporator array on substrates with equal quality;
wherein the spatial emission characteristic of a metallic evaporator element is an angular dependence of a flow density of evaporated material of that metallic evaporator element, and wherein the angle between the evaporator array and each substrate carrier unit is equivalent.

### Claim 14

A method for the vacuum coating of substrates, characterized in that the vacuum coating is carried out by means of a device as claimed in one of the preceding claims.

### Claim 15 (depends on 14)

The method as claimed in claim 14, characterized in that thermal evaporation of a metallic material, in particular consisting of at least one of the members of the group consisting of aluminum, copper, tin, chromium, titanium, tantalum, gold, silver, rhodium, palladium and nickel, is carried out by means of the evaporator array (10, 110, 110a).

### Claim 16 (depends on 14, 15)

The method as claimed in one of claims 14 and 15, characterized in that treatment of the substrates with the aid of a glow discharge process is carried out by means of at least one of the treatment sources (31, 32).

### Claim 17 (depends on 14, 15, 16)

The method as claimed in one of claims 14 to 16, characterized in that treatment of the substrates with the aid of a plasma CVD process is carried out by means of at least one of the treatment sources (31, 32).
