# US 10,767,243 B2 · Purification process

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- Number: US 10,767,243 B2
- Document ID: US10767243B2
- Status: Granted
- Kind: B2
- Application number: 15/826,280
- Filed: 2017-11-29
- Published: 2018-05-24
- Granted: 2020-09-08
- Earliest claimed: 2010-08-04
- Assignees: Curium US LLC
- Applicants: Curium US LLC
- Inventors: Luis A. M. M. Barbosa
- Web page: https://patentgrep.com/patent/US10767243B2

## CPC

- C22B 34/34: Obtaining molybdenum {(treatment or purification of solutions by adsorption on solids C22B3/24, by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42; preparation of molybdenum involving liquid-liquid extraction, adsorption or ion-exchange C01G39/003)}
- G21G 1/001: {Recovery of specific isotopes from irradiated targets}
- G21G 2001/0036: {Molybdenum}
- C22B: PRODUCTION AND REFINING OF METALS (electrolytic C25); PRETREATMENT OF RAW MATERIALS
- G21G: CONVERSION OF CHEMICAL ELEMENTS; RADIOACTIVE SOURCES (applications of radiation in general G21H5/00; handling particles, e.g. neutrons, or electromagnetic radiation not otherwise provided for G21K)

## Abstract

A process for purifying Mo-99 from an acidic solution obtained by dissolving an irradiated solid target comprising uranium in an acidic medium, or from an acidic solution comprising uranium and which has previously been irradiated in a nuclear reactor, or from an acidic solution comprising uranium and which has been used as reactor fuel in a homogeneous reactor, the process comprising contacting the acidic solution with an adsorbent comprising a zirconium oxide, zirconium hydroxide, zirconium alkoxide, zirconium halide and/or zirconium oxide halide, and eluting the Mo-99 from the adsorbent using a solution of a strong base, the eluate then being subjected to a subsequent purification process involving an alkaline-based Mo-99 chromatographic recovery step on an anion exchange material. Also provided is apparatus for carrying out the process.

## Claims

### Claim 1

An apparatus for carrying out a process for purifying Mo-99, the apparatus comprising:
a column or vessel containing an adsorbent comprising a zirconium oxide, zirconium hydroxide, zirconium alkoxide, zirconium halide and/or zirconium oxide halide; a source of a solution of a strong base, the source of strong base solution being arranged in fluid communication at an inlet of the column or vessel containing the adsorbent;
a column or vessel containing an anion exchange material on which Mo-99 can be quantitatively adsorbed and arranged in downstream fluid communication with the column or vessel containing the adsorbent;
a source of a solution of an acid, the source of acid solution being arranged in fluid communication at an inlet of the column or vessel containing the anion exchange material; and
a column or vessel containing MnO2 material and arranged in downstream fluid communication with the column or vessel containing the anion exchange material;
a source of a solution of sulfuric acid containing thiocyanide ions and a reducing agent, the source of sulfuric acid solution containing thiocyanide ions and a reducing agent being arranged in fluid communication at an inlet of the column or vessel containing the MnO2 material;
and a column or vessel containing an ion exchange material comprising iminodiacetate groups and arranged in downstream fluid communication with the column or vessel containing the MnO2 material.

### Claim 2 (depends on 1)

An apparatus of claim 1, wherein the adsorbent further comprises a titanium oxide and/or silicon oxide.

### Claim 3 (depends on 1)

An apparatus of claim 1, wherein the zirconium compound is present at a concentration of from 5 to 70 mol % of the adsorbent.

### Claim 4 (depends on 1)

An apparatus of claim 1, wherein the adsorbent is in the form of pellets.