# US 10,767,139 B2 · Synergistic protein soil removal through novel chelator combination

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- Number: US 10,767,139 B2
- Document ID: US10767139B2
- Status: Granted
- Kind: B2
- Application number: 15/554,347
- Filed: 2015-03-04
- Published: 2018-02-15
- Granted: 2020-09-08
- Earliest claimed: 2015-03-04
- Assignees: Ecolab USA Inc.
- Applicants: Ecolab USA Inc.
- Inventors: Timothy Meier; David Dotzauer; Tobias Neil Foster; John Mansergh
- Web page: https://patentgrep.com/patent/US10767139B2

## CPC

- C11D 3/33: Amino carboxylic acids
- C11D 1/66: Non-ionic compounds {(C11D1/002, C11D1/004, C11D1/008 take precedence)}
- C11D 3/06: Phosphates, including polyphosphates
- C11D 3/10: Carbonates {; Bicarbonates}
- C11D 2111/14: Hard surfaces
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

## Abstract

The invention relates to a concentrated detergent composition comprising surfactant, alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove protein soil in warewashing applications.

## Claims

### Claim 1

A concentrated detergent composition comprising:
from 0.5 wt. % to 5 wt. % of a nonionic surfactant,
at least 52 wt. % of an alkali metal carbonate, and
chelating/sequestering agents, wherein the chelating/sequestering agents comprise of from 5 wt. % to 25 wt. % of methyl glycine diacetic acid, from 5 wt. % to 10 wt. % glutamic acid N,N-diacetic acid, and from 5 wt. % to 17 wt. % of an alkali metal tripolyphosphate;
wherein the detergent composition removes protein soil;
wherein the total quantity of the chelating/sequestering agents is less than 45 wt. % of the composition; and
wherein the molar ratio of the glutamic acid N,N-diacetic acid to the sum of the methyl glycine diacetic acid and the alkali metal tripolyphosphate is 0.05 to 2 further wherein the wt % of each component is based on the total weight of the composition.

### Claim 2 (depends on 1)

The concentrated detergent composition according to claim 1, wherein the composition comprises from 60 wt. % to 80 wt. % alkali metal carbonate.

### Claim 3 (depends on 1)

The concentrated detergent composition according to claim 1, wherein the molar ratio of methyl glycine acid to alkali metal tripolyphosphate is 0.14 to 14.3.

### Claim 4 (depends on 1)

The concentrated detergent composition according to claim 1, wherein the nonionic surfactant is selected from polyethylene glycol ethers of fatty alcohols, polyalkylene oxide free nonionics, sorbitan esters and ethoxylates thereof, sucrose esters and ethoxylates thereof, alkoxylated ethylene diamines, alcohol alkoxylates, nonylphenol ethoxylates, polyoxyethylene glycol ethers, carboxylic acid esters and ethoxylates thereof, carboxylic amides, polyalkylene oxide block copolymers, ethylene oxide-propylene oxide block copolymers, or a combination thereof.

### Claim 5 (depends on 1)

The concentrated detergent composition according to claim 1, wherein the molar ratio of the sum of glutamic acid N,N-diacetic acid, methyl glycine diacetic acid and alkali metal tripolyphosphate to alkali metal carbonate is 0.01 to 0.5.

### Claim 6 (depends on 1)

The concentrated detergent composition according to claim 1, wherein the alkali metal carbonate is sodium or potassium carbonate, sodium or potassium bicarbonate, sodium or potassium sesquicarbonate, or a combination thereof.

### Claim 7 (depends on 1)

The concentrated detergent composition according to claim 1, wherein the alkali metal tripolyphosphate is sodium tripolyphosphate.

### Claim 8 (depends on 1)

The concentrated detergent composition according to claim 1, wherein the composition provides a pH of at least 6 when diluted in distilled water at a concentration of 1 g/l and measured at 20° C.

### Claim 9 (depends on 1)

The concentrated detergent composition according to claim 1, wherein the composition further comprises one or more of bleaching agents, activating agents, silicates, detergent fillers or binding agents, defoaming agents, anti-redeposition agents, enzymes, dyes, odorants, catalysts, threshold polymers, soil suspension agents, antimicrobials or a combination thereof.

### Claim 10 (depends on 1)

The concentrated detergent composition according to claim 1, wherein the composition is provided in the form of a solid, a powder, a liquid, a gel, or a paste.

### Claim 11 (depends on 1)

A method of removing soil comprising protein in an automatic dishwashing machine, said method comprising contacting a soiled surface with the composition according to claim 1.

### Claim 12 (depends on 11)

The method according to claim 11, wherein the concentrated detergent composition is diluted to provide a use solution with a concentration of 0.1 to 10 g/l.

### Claim 13 (depends on 12)

The method according to claim 12, wherein the concentrated detergent composition is diluted with water having a hardness of at least 50 mg/l CaCO3.