# US 10,766,255 B2 · Element substrate > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,766,255 B2 - Document ID: US10766255B2 - Status: Granted - Kind: B2 - Application number: 16/369,263 - Filed: 2019-03-29 - Published: 2019-10-10 - Granted: 2020-09-08 - Earliest claimed: 2018-04-04 - Assignees: Canon Kabushiki Kaisha - Applicants: Canon Kabushiki Kaisha - Inventors: Shinya Iwahashi; Mineo Shimotsusa; Sadayoshi Sakuma - Web page: https://patentgrep.com/patent/US10766255B2 ## CPC - B41J 2/14129: {Layer structure} - B41J: TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS ## Abstract Provided is an element substrate with suppressed variations in resistance though having a high resistance. In an element substrate equipped with a heat generating resistor that generates thermal energy for ejecting a liquid, the heat generating resistor is a stacked structure having stacked a plurality of resistor layers including a first resistor layer and a second resistor layer containing a metal silicon nitride and the first resistor layer and the second resistor layer are different from each other in at least one of a silicon content in the metal silicon oxide and a metal element contained in the metal silicon nitride. ## Claims ### Claim 1 An element substrate comprising a heat generating resistor that generates thermal energy for ejecting a liquid, wherein the heat generating resistor is a stacked structure having stacked a plurality of resistor layers including a first resistor layer and a second resistor layer, each containing a metal silicon nitride and the first resistor layer and the second resistor layer being different in at least one of a silicon content in the metal silicon nitride and a metal element contained in the metal silicon nitride, and wherein when the second resistor layer has a specific resistance value not more than that of the first resistor layer, a ratio of the specific resistance value of the first resistor layer to the specific resistance value of the second resistor layer is 2 or less. ### Claim 2 (depends on 1) The element substrate according to claim 1, wherein the first resistor layer and the second resistor layer are different from each other in the silicon content in the metal silicon nitride. ### Claim 3 (depends on 1) The element substrate according to claim 1, wherein the first resistor layer and the second resistor layer are different from each other in the metal element contained in the metal silicon nitride. ### Claim 4 (depends on 3) The element substrate according to claim 3, wherein the first resistor layer is made of a tungsten silicon nitride and the second resistor layer is made of a tantalum silicon nitride. ### Claim 5 (depends on 4) The element substrate according to claim 4, wherein the silicon content in the first resistor layer is larger than the silicon content in the second resistor layer. ### Claim 6 An element substrate comprising a heat generating resistor that generates thermal energy for ejecting a liquid, wherein the heat generating resistor is a stacked structure having stacked a plurality of resistor layers including a first resistor layer showing a resistance value decreasing tendency by driving and a second resistor layer showing a resistance value increasing tendency by driving. ### Claim 7 (depends on 6) The element substrate according to claim 6, wherein when the second resistor layer has a specific resistance not more than a specific resistance of the first resistor layer, a ratio of the specific resistance of the first resistor layer to the specific resistance of the second resistor layer is 2 or less. ### Claim 8 (depends on 6) The element substrate according to claim 6, wherein the first resistor layer after it is driven continuously at a predetermined times or more has a smaller resistance than the first resistor layer before it is driven and the second resistance layer after it is driven continuously at the predetermined times or more has a larger resistance than the second resistor layer before it is driven. ### Claim 9 (depends on 6) The element substrate according to claim 6, wherein the first resistor layer after it is driven continuously 1×108 times or more has a lower resistance than that before it is driven. ### Claim 10 (depends on 6) The element substrate according to claim 6, wherein the second resistor layer after it is driven continuously 1×108 times or more has a higher resistance than that before it is driven. ### Claim 11 (depends on 6) The element substrate according to claim 6, wherein at least one of the first resistor layer and the second resistor layer is a metal silicon nitride. ### Claim 12 An element substrate comprising a heat generating resistor that generates thermal energy for ejecting a liquid, wherein the heat generating resistor is a stacked structure having stacked a plurality of resistor layers including a first resistor layer and a second resistor layer, each containing a metal silicon nitride and the first resistor layer and the second resistor layer being different in at least one of a silicon content in the metal silicon nitride and a metal element contained in the metal silicon nitride, wherein the first resistor layer and the second resistor layer are different from each other in the silicon content in the metal silicon nitride, and wherein the silicon content in the first resistor layer is from 35 at % to 45 at % and the silicon content in the second resistor layer is from 15 at % to 25 at %. ### Claim 13 (depends on 12) The element substrate according to claim 12, wherein the first resistor layer and the second resistor layer are different from each other in the metal element contained in the metal silicon nitride. ### Claim 14 (depends on 13) The element substrate according to claim 13, wherein the first resistor layer is made of a tungsten silicon nitride and the second resistor layer is made of a tantalum silicon nitride. ### Claim 15 An element substrate comprising a heat generating resistor that generates thermal energy for ejecting a liquid, wherein the heat generating resistor is a stacked structure having stacked a plurality of resistor layers including a first resistor layer and a second resistor layer, each containing a metal silicon nitride and the first resistor layer and the second resistor layer being different in at least one of a silicon content in the metal silicon nitride and a metal element contained in the metal silicon nitride, and wherein the first resistor layer shows a resistance value decreasing tendency by driving and the second resistor layer shows a resistance value increasing tendency by driving. ### Claim 16 (depends on 15) The element substrate according to claim 15, wherein the first resistor layer and the second resistor layer are different from each other in the silicon content in the metal silicon nitride. ### Claim 17 (depends on 15) The element substrate according to claim 15, wherein the first resistor layer and the second resistor layer are different from each other in the metal element contained in the metal silicon nitride. ### Claim 18 (depends on 17) The element substrate according to claim 17, wherein the first resistor layer is made of a tungsten silicon nitride and the second resistor layer is made of a tantalum silicon nitride. ### Claim 19 (depends on 18) The element substrate according to claim 18, wherein the silicon content in the first resistor layer is larger than the silicon content in the second resistor layer.