# US 10,765,569 B2 · Synthetic surfactant-free finish, sheet having synthetic surfactant-free finish, articles having sheet with synthetic surfactant-free finish, and related methods

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- Number: US 10,765,569 B2
- Document ID: US10765569B2
- Status: Granted
- Kind: B2
- Application number: 15/707,603
- Filed: 2017-09-18
- Published: 2018-01-04
- Granted: 2020-09-08
- Earliest claimed: 2014-11-14
- Assignees: Attends Healthcare Products, Inc.
- Applicants: Attends Healthcare Products, Inc.
- Inventors: Harry J. Chmielewski; Edward L. Seames
- Web page: https://patentgrep.com/patent/US10765569B2

## CPC

- A61F 13/513: {characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect;} having areas of different permeability
- A61F 13/51113: {comprising an additive, e.g. lotion or odour control (A61F13/51108 takes precedence)}
- A61L 15/24: Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof {(A61L15/225 takes precedence)}
- A61L 15/32: Proteins, polypeptides; Degradation products or derivatives thereof, e.g. albumin, collagen, fibrin, gelatin {(A61L15/225 takes precedence)}
- A61L 15/62: {Compostable,} hydrosoluble or hydrodegradable materials
- C09D 189/00: Coating compositions based on proteins; Coating compositions based on derivatives thereof
- A61F: FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS (dental prosthetics A61C)
- A61L: METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES (preservation of bodies or disinfecting characterised by the agents employed A01N; preserving, e.g. sterilising, food or foodstuffs A23; preparations for medical, dental or toiletry purposes A61K)
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)

## Abstract

Nonwoven (and film) topsheet and acquisition/distribution materials treated with a hydrophilic, synthetic surfactant-free finish, absorbent articles for infant or incontinence care that contain these materials, and methods for apply such finishes and/or making such absorbent articles.

## Claims

### Claim 1

A hydrophilic, synthetic sheet comprising:
a sheet of synthetic material having a first surface;
where the sheet comprises a hydrophilic finish including molecules of a water-soluble protein dispersed on the first surface;
where the finish includes substantially no synthetic surfactants;
where a 0.5-10% aqueous solution of the water-soluble protein has a surface tension of less than 49 milliNewtons per meter (mN/m); and
the water-soluble protein comprises soy protein isolate.

### Claim 2 (depends on 1)

The sheet of claim 1, wherein the finish does not include synthetic materials capable of reducing the surface tension of water below 50 mN/m.

### Claim 3 (depends on 1)

The sheet of claim 1, wherein the sheet comprises a nonwoven fabric or a film.

### Claim 4 (depends on 1)

The sheet of claim 1, where the sheet is a topsheet of an absorbent article.

### Claim 5 (depends on 1)

The sheet of claim 1, wherein the sheet is a distribution-acquisition layer of an absorbent article.

### Claim 6 (depends on 1)

The sheet of claim 1, wherein the water-soluble protein comprises a thermally-denatured protein.

### Claim 7 (depends on 1)

The sheet of claim 1, wherein a 1.2-10% aqueous solution of the water-soluble protein has a surface tension of less than 49 mN/m.

### Claim 8 (depends on 1)

The sheet of claim 1, wherein at least 0.004 grams of the molecules of the water-soluble protein are dispersed on the sheet for each gram of sheet.

### Claim 9 (depends on 1)

A disposable absorbent article comprising:
a topsheet comprising the sheet of claim 1;
a backsheet; and
an absorbent core disposed between the topsheet and the backsheet.

### Claim 10 (depends on 1)

A disposable absorbent article comprising:
a topsheet;
a distribution-acquisition layer comprising the sheet of claim 1;
a backsheet; and
an absorbent core disposed between the distribution-acquisition layer and the backsheet.

### Claim 11

A method of imparting hydrophilic properties to a sheet of polymeric material, the method comprising:
applying a 0.5-10% aqueous solution of a water-soluble protein having a surface tension of less than 49 milliNewtons per meter (mN/m) to a sheet of polymeric material in an aqueous solution; and
drying the sheet such that at least a portion of the protein is retained on a surface of the sheet;
where the aqueous solution is substantially free of synthetic surfactants; and
where the protein comprises soy protein isolate.

### Claim 12

A finish for a synthetic nonwoven or film, the finish comprising:
an 0.5-10% aqueous solution of a water-soluble, thermally-denatured protein, the solution having a surface tension less than 49 milliNewtons per meter (mN/m);
where the aqueous solution is substantially free of synthetic surfactants; and
where the protein comprises soy protein isolate.
