Cathode active material, method for manufacturing same, and lithium secondary battery comprising same
AssigneeIucf-Hyu (Industry-University Cooperation Foundation Hanyang University)
InventorsYang-Kook Sun, Un Hyuck Kim
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Abstract
A method for manufacturing a positive active material is provided. The method includes forming a positive active material precursor including nickel, mixing and firing the positive active material precursor and lithium salt to form a preliminary positive active material particle, forming a coating material including fluorine on the preliminary positive active material particle by dry-mixing the preliminary positive active material particle with a coating source including fluorine, and manufacturing a positive active material particle by thermally treating the preliminary positive active material particle on which the coating material is formed.
Claims9
A method for manufacturing a positive active material, the method comprising:
- forming a positive active material precursor including nickel;
- mixing and firing the positive active material precursor and a lithium salt to form a preliminary positive active material particle;
- forming a coating material including fluorine on the preliminary positive active material particle by dry-mixing the preliminary positive active material particle with a coating source including fluorine;
- and
- manufacturing a positive active material particle by thermally treating the preliminary positive active material particle on which the coating material is formed, at a temperature lower than a crystal structure changing temperature of the positive active material particle, said crystal structure changing temperature being a temperature where the fluorine included in the coating source permeates into a crystal lattice of the positive active material particle,
- wherein the positive active material particle comprises nickel, and
- wherein the crystal structure changing temperature decreases as a content of nickel included in the positive active material particle increases.
Dependencies are inferred from the claim text.