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US 10,763,444 B2Granted
Organic electroluminescence device and electronic apparatus provided with the same
AssigneeIdemitsu Kosan Co., Ltd.
InventorsYuki Nakano, Taro Yamaki, Satomi Tasaki, Tomoki Kato
Life of this patent
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Abstract
An organic electroluminescence device including a cathode, an anode, and an emitting layer disposed between the cathode and the anode, wherein the emitting layer includes a compound represented by the following formula (1) and one or more compounds selected from the group consisting of compounds represented by formulas (11), (21), (31), (41), (51), (61), (71) and (81). In the formula (1), at least one of R1 to R8 is a deuterium atom.
Claims30
An organic electroluminescence device comprising:
- a cathode,
- an anode, and
- an emitting layer disposed between the cathode and the anode, wherein
- the emitting layer comprises a compound represented by the following formula (1) and a compound represented by the following formula (31):
- wherein in the formula (1),
- R1 to R8 are independently
- a hydrogen atom,
- a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
- a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
- a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
- a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
- —Si(R901)(R902)(R903),
- —O—(R904),
- —S—(R905),
- —N(R906)(R907),
- a halogen atom, a cyano group, a nitro group,
- a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
- a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
- R901 to R907 are independently
- a hydrogen atom,
- a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
- a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
- a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
- a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
- when two or more of R901 to R907 exist, two or more of R901 to R907 may be the same with or different from each other;
- at least one of R1 to R4 is a deuterium atom;
- two or more adjacent groups of R1 to R4 and two or more adjacent groups of R5 to R8 do not form a ring;
- L1 and L2 are independently
- a single bond,
- a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or
- a substituted or unsubstituted divalent heterocyclic group having 5 to 30 ring atoms;
- Ar is
- a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
- a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
- one of R11 to R18 is a single bond bonding to L2;
- R11 to R18 which are not single bonds bonding to L2 are independently
- a hydrogen atom,
- a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
- a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
- a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
- a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
- —Si(R901)(R902)(R903),
- —O—(R904),
- —S—(R905),
- —N(R906)(R907),
- a halogen atom, a cyano group, a nitro group,
- a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
- a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
- R901 to R907 are as defined in R1 to R8;
- and
- two or more adjacent groups of R11 to R18 do not form a ring;
- wherein in the formula (31),
- one or more pairs of two or more adjacent groups of R301 to R307 and R311 to R317 form a substituted or unsubstituted, saturated or unsaturated ring, or do not form a substituted or unsubstituted, saturated or unsaturated ring;
- R301 to R307 and R311 to R317 that do not form the substituted or unsubstituted, saturated or unsaturated ring are independently
- a hydrogen atom,
- a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
- a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
- a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
- a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
- —Si(R901)(R902)(R903),
- —O—(R904),
- —S—(R905),
- —N(R906)(R907),
- a halogen atom, a cyano group, a nitro group,
- a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
- a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
- R321 and R322 are independently
- a hydrogen atom,
- a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms,
- a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms,
- a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms,
- a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,
- —Si(R901)(R902)(R903),
- —O—(R904),
- —S—(R905),
- —N(R906)(R907),
- a halogen atom, a cyano group, a nitro group,
- a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or
- a substituted or unsubstituted monovalent heterocyclic group having 5 to 50 ring atoms;
- and
- R901 to R907 are as defined in the formula (1).
78 more elements
Dependencies are inferred from the claim text.