Polymerizable polar compound, liquid crystal composition and liquid crystal display element
AssigneesJnc Corporation, Jnc Petrochemical Corporation
InventorHiroyuki Tanaka
Life of this patent
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Abstract
To provide a polar compound having high chemical stability, a high ability to align liquid crystal molecules, and high solubility in a liquid crystal composition, and a high voltage holding ratio of a liquid crystal display element. A compound represented by Formula (1): R1 is a hydrogen atom or an alkyl group that may be substituted; a is 2 to 12; and R2 is Formula (1-a), Formula (1-b), and Formula (1-c); Sp1 to Sp3 are a single bond or an alkylene group that may be substituted; M1 and M2 are H, F, Cl, or an alkyl group that may be substituted; and X1 is —OH, —NH2, —OR3, —N(R3)2, —COOH, —SH or —Si(R3)3.
Claims20
A compound represented by Formula (1):
- in Formula (1),
- R1 is an alkyl group having 1 to 15 carbon atoms, and in this alkyl group, at least one —CH2— is optionally substituted with —O— or —S—, and at least one —(CH2)2— is optionally substituted with —CH═CH— or —C≡C—, and in these groups represented by R1, at least one hydrogen atom is optionally substituted with a fluorine or chlorine atom;
- a is an integer of 2 to 12;
- M1 and M2 are independently a hydrogen atom, a fluorine atom, a chlorine atom, an alkyl group having 1 to 5 carbon atoms, or an alkyl group having 1 to 5 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom or a chlorine atom;
- and
- R2 is a group selected from among groups represented by Formula (1-a), Formula (1-b), and Formula (1-c);
- in Formula (1-a), Formula (1-b), and Formula (1-c),
- Sp2 and Sp3 are independently a single bond or an alkylene group having 1 to 10 carbon atoms, and in this alkylene group, at least one —CH2— is optionally substituted with —O—, —CO—, —COO—, —OCO—, or —OCOO—, and at least one —(CH2)2— is optionally substituted with —CH═CH— or —C≡C—, and in these groups represented by Sp2 and Sp3, at least one hydrogen atom is optionally substituted with a fluorine or chlorine atom;
- R3 is a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 9 carbon atoms, or an alkoxyalkyl group having 1 to 9 carbon atoms;
- X1 is independently —OH, —NH2, —N(R4)2, —COOH, —SH, or —Si(R4)3;
- in —N(R4)2, and —Si(R4)3,
- R4 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, and in this alkyl group, at least one —CH2— is optionally substituted with —O—, and at least one —(CH2)2— is optionally substituted with —CH═CH—, and in these groups represented by R4, at least one hydrogen atom is optionally substituted with a fluorine or chlorine atom,
- in Formula (1),
- Sp1 is a single bond or an alkylene group having 1 to 15 carbon atoms, and in this alkylene group, at least one —CH2— is optionally substituted with —O—, —CO—, —COO—, —OCO—, or —OCOO—, and at least one —(CH2)2— is optionally substituted with —CH═CH— or —C≡C—, and in these groups represented by Sp1, at least one hydrogen atom is optionally substituted with a fluorine atom, a chlorine atom, or a group represented by Formula (1-d);
- in Formula (1-d),
- Sp4 is a single bond or an alkylene group having 1 to 10 carbon atoms, and in this alkylene group, at least one —CH2— is optionally substituted with —O—, —CO—, —COO—, —OCO—, or —OCOO—, and at least one —(CH2)2— is optionally substituted with —CH═CH— or —C≡C—, and in these groups represented by Sp4, at least one hydrogen atom is optionally substituted with a fluorine or chlorine atom;
- M3 and M4 are independently a hydrogen atom, a fluorine atom, a chlorine atom, an alkyl group having 1 to 5 carbon atoms, or an alkyl group having 1 to 5 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom or a chlorine atom;
- and
- R5 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, and in this alkyl group, at least one —CH2— is optionally substituted with —O—, at least one —(CH2)2— is optionally substituted with —CH═CH— or —C≡C—, and at least one hydrogen atom is optionally substituted with a fluorine atom or a chlorine atom.
Dependencies are inferred from the claim text.