Copolymers having a gradient structure as dispersant for alkalinically activated binding agents
AssigneeSika Technology AG
InventorsJürg Weidmann, Lukas Frunz, Jörg Zimmermann
Life of this patent
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Abstract
A copolymer as dispersant in a binder composition comprising an alkaline activating agent, wherein the activating agent is especially suitable for activation of a latently hydraulic and/or pozzolanic binder, wherein the copolymer has a polymer backbone and side chains bonded thereto and comprises at least one ionizable monomer unit M1 and at least one side chain-bearing monomer unit M2, and wherein the copolymer has a gradient structure in at least one section A in a direction along the polymer backbone with regard to the ionizable monomer unit M1 and/or with regard to the side chain-bearing monomer unit M2.
Claims21
A binder composition comprising:
- an organic binder and/or a mineral binder,
- an alkaline activating agent, and
- a copolymer, as dispersant, having a polymer backbone and side chains bonded thereto and comprising:
- at least one ionizable monomer unit M1, and
- at least one side chain-bearing monomer unit M2,
- wherein:
- the copolymer has a gradient structure in at least one section A in a direction along the polymer backbone with regard to the ionizable monomer unit M1 and/or with regard to the side chain-bearing monomer unit M2,
- the copolymer has a further section B, where there is essentially a constant local concentration of monomers and/or a statistical or random distribution of monomers over the entire section B,
- the ionizable monomer unit M1 has a structure represented by formula I:
- and the side chain-bearing monomer unit M2 includes a structure represented by formula II:
- where:
- R1, in each case independently, is —COOM, —SO2—OM, —OPO(OM)2, or —PO(OM)2,
- R2, R3, R5, and R6, in each case independently, are H or an alkyl group having 1 to 5 carbon atoms,
- R4 and R7, in each case independently, are H, —COOM, or an alkyl group having 1 to 5 carbon atoms, or R1 forms a ring together with R4 to give —CO—O—CO—,
- M, independently of one another, represents H+, an alkali metal ion, an alkaline earth metal ion, a di- or trivalent metal ion, an ammonium ion, or an organic ammonium group,
- m=0, 1, or 2,
- p=0 or 1,
- X, in each case independently, is —O— or —NH—,
- R8 is a group represented by formula -[AO]n—Ra, where A is a C2- to C4-alkylene, Ra is H, a C1- to C20-alkyl group, a cycloalkyl group, or an alkylaryl group, and
- n=2-250.
Dependencies are inferred from the claim text.