Production of phosphate compounds from materials containing phosphorus and at least one of iron and aluminium
AssigneeEasymining Sweden AB
InventorsYariv Cohen, Patrik Enfält
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Abstract
A method for production of phosphate compounds comprises dissolving of a raw material comprising phosphorus, aluminium and iron, in a mineral acid. Insoluble residues from the dissolving step are separated. Iron hydroxide is added causing precipitation of phosphate compounds. The precipitated phosphate compounds are removed. The phosphate compounds are dissolved by an alkaline solution. Iron hydroxide is filtered out. Lime is added, causing precipitation of calcium phosphate. The precipitated calcium phosphate is separated. The leach solution after the separating of precipitated calcium phosphate is recycled to be used for dissolving phosphate compounds by an alkaline solution.
Claims6
A method for the production of phosphate compounds, comprising the steps of:
- dissolving a raw material comprising sludge ash, comprising phosphorus, aluminium and iron, in a liquid comprising at least mineral acid;
- separating insoluble residues from said dissolving step, thereby forming a primary leach solution;
- adding a base comprising iron hydroxide to said primary leach solution, after said step of separating insoluble residues, causing precipitation of phosphate compounds comprising iron and aluminium from said primary leach solution;
- removing said precipitated phosphate compounds from said primary leach solution;
- dissolving said phosphate compounds by an alkaline solution into a second leach solution;
- filtering iron hydroxide from said second leach solution;
- adding lime into said second leach solution after said step of filtering iron hydroxide, causing precipitation of calcium phosphate;
- separating precipitated calcium phosphate from said second leach solution;
- recycling said second leach solution after said step of separating precipitated calcium phosphate to be used in said step of dissolving phosphate compounds by an alkaline solution.
Dependencies are inferred from the claim text.