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US 10,724,117 B2Granted
Method of recovering base metals from low grade ores and residues
AssigneeSirch Group (Pty) Ltd.
InventorsNicholas Conradie, Marthie Kotze
Life of this patent
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Abstract
A method of recovering a metal from a low-grade ore which is subjected to cyanide leaching to produce a PLS which contains a metal cyanide which is removed from the PLS by ultrafiltration and nano-filtration, and then acidified and sulphidised to produce a metal sulphide from which the metal is extracted, and hydrogen cyanide which is recycled to the cyanide leaching step.
Claims4
A method for the recovery of at least one metal from a low grade metal sulphide ore or residue, wherein the method includes the following steps:
- a) cyanide-leaching the low grade ore or residue, at an alkaline pH of between 10 and 11, to produce a pregnant leach solution which contains at least one metal cyanide;
- b) upgrading the pregnant leach solution by removing leached or barren solids from the pregnant leach solution;
- c) subjecting the upgraded pregnant leach solution to ultrafiltration to produce a clarified liquor;
- d) subjecting the clarified liquor to nano-filtration so as to separate metal cyanide complexes in a retentate from free cyanide in a permeate, thereby to produce a metal cyanide concentrate and a permeate containing free cyanide;
- e) subjecting the permeate to a reverse osmosis process to form a high-quality water stream and a free cyanide concentrate which is recycled to the cyanide leaching step a);
- f) subjecting the metal cyanide concentrate to acidification by the addition of sulphuric acid to lower the pH thereof to a value between 2 and 6 and then to sulphidisation to produce a solution which contains a metal-sulphide and hydrogen cyanide;
- g) subjecting the solution formed in step f) to a solid/liquid separation step, thereby to recover at least some of the metal sulphide and at least some of the hydrogen cyanide;
- and
- h) recycling the recovered hydrogen cyanide to the cyanide leaching (step a)).
6 more elements
Dependencies are inferred from the claim text.