Quantum dots, a composition or composite including the same, and an electronic device including the same
AssigneesSamsung Display Co., Ltd., Samsung SDI Co., Ltd., Samsung Electronics Co., Ltd.
InventorsJooyeon Ahn, Ha Il Kwon, Shang Hyeun Park, Nayoun Won, Eun Joo Jang, Shin Ae Jun
Life of this patent
Estimating the term…
Abstract
A quantum dot including a first ligand and a second ligand on a surface of the quantum dot, a composition or composite including the same, and a device including the same. The first ligand includes a compound represented by Chemical Formula 1 and the second ligand includes a compound represented by Chemical Formula 2: MAn Chemical Formula 1 wherein M, n, and A are the same as defined in the specification; and wherein, R1, L1, Y1, R, k1, and k2 are the same as defined in the specification.
Claims29
A quantum dot comprising:
- a semiconductor nanocrystal particle;
- a first ligand bound to a surface of the semiconductor nanocrystal particle;
- and
- a second ligand bound to the surface of the semiconductor nanocrystal particle,
- wherein the second ligand comprises a compound represented by Chemical Formula 2-1, Chemical Formula 2-2, or Chemical Formula 2-3:
- Ra-L-(CRR)nSM Chemical Formula 2-1
- RRNCSSM Chemical Formula 2-3
- wherein
- Ra includes a substituted or unsubstituted C1 to C24 alkyl group, a substituted or unsubstituted C2 to C24 alkenyl group, and a substituted or unsubstituted C6 to C20 aryl group, R is the same or different, and is each independently hydrogen or a substituted or unsubstituted C1 to C24 alkyl group, n is an integer of 0 to 15, L is a direct bond, a sulfonyl (—S(═O)2—), carbonyl (—C(═O)—), ether group (—O—), sulfide group (—S—), sulfoxide group (—S(═O)—), ester group (—C(═O)O—), amide group (—C(═O)NR—) (wherein R is hydrogen or a C1 to C10 alkyl group), a substituted or a unsubstituted C1 to C10 alkylene, a C2 to C10 alkenylene, or a combination thereof, and M is hydrogen, lithium, sodium, potassium, or a combination thereof
- wherein the first ligand comprises a compound represented by Chemical Formula 1:
- MAn Chemical Formula 1
- wherein M is Mg, Ca, Zn, Ga, or In, n is determined depending on a valency of the M and is an integer of greater than or equal to 2, each A is the same or different, and is independently a C1 to C10 organic group, a halogen, or a combination thereof, and
- wherein the first ligand comprises an organic metal salt, a halogenated metal, a hydrocarbyl metal, a hydrocarbyl metal halide, or a combination thereof,
- wherein when a plurality of the quantum dots are included in a composition comprising a binder polymer having a carboxylic acid group and the composition is left at 4° C. for 144 hours, an increase of a viscosity of the composition is less than about 10% with respect to an initial viscosity of the composition.
Dependencies are inferred from the claim text.