Processing tape for optical articles
Assignee3M Innovative Properties Company
InventorsLan H. Liu, Edward J. Kivel, Steven D. Solomonson, Stephen A. Johnson
Life of this patent
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Abstract
Processing tapes for use in preparing optical articles include a thermally stable tape backing and a low tack adhesive layer at least partially coated on tape backing. The low tack adhesive layer includes a crosslinked, polyester-containing (meth)acrylate-based polymer that is essentially free of volatile components, is unchanged after heat aging of 150 C for 1 hour under a pressure of 4.31 kiloPascals, and is able to removably adhere to the anti-reflective, nanostructured surface coating of an optical construction.
Claims18
A tape comprising:
- a thermally stable tape backing with a first major surface and a second major surface;
- and a low tack adhesive layer at least partially coated on the first major surface of the
- tape backing, wherein the low tack adhesive layer comprises a crosslinked, polyester-containing (meth)acrylate-based polymer that is essentially free of volatile components, is unchanged after heat aging of 150° C. for 1 hour under a pressure of 4.31 kiloPascals, and is able to removably adhere to an anti-reflective, nanostructured surface coating of an optical construction, wherein the polyester-containing (meth) acrylate-based polymer is prepared from a reaction mixture comprising:
- at least one multifunctional polyester-containing (meth) acrylate;
- at least one polyester-containing (meth) acrylate oligomer;
- and an initiator.
An optical laminate comprising:
- an optical construction comprising:
- a heat resistant film comprising a first major surface and a second major surface, with an anti-reflective, nanostructured surface coating on the second major surface;
- and
- a tape removably adhered to the anti-reflective, nanostructured surface coating on the second major surface of the optical construction, the tape comprising:
- a thermally stable tape backing with a first major surface and a second major surface;
- and
- a low tack adhesive layer at least partially coated on the first major surface of the tape backing, wherein the low tack adhesive layer comprises a crosslinked, polyester-containing (meth)acrylate-based polymer that is essentially free of volatile components, is unchanged after heat aging of 150° C. for 1 hour under a pressure of 4.31 kiloPascals, wherein the polyester-containing (meth) acrylate-based polymer is prepared from a reaction mixture comprising:
- at least one multifunctional polyester-containing (meth) acrylate;
- at least one polyester-containing (meth) acrylate oligomer;
- and an initiator.
A method of preparing an optical article comprising:
- providing an optical construction comprising:
- a heat resistant film comprising a first major surface and a second major surface, with an anti-reflective, nanostructured surface coating on the second major surface;
- providing a tape, the tape comprising:
- a thermally stable tape backing with a first major surface and a second major surface;
- and
- a low tack adhesive layer at least partially coated on the first major surface of the tape backing, wherein the adhesive layer comprises a crosslinked, polyester-containing (meth)acrylate-based polymer that is essentially free of volatile components, is unchanged after heat aging of 150° C. for 1 hour under a pressure of 4.31 kiloPascals, wherein the polyester-containing (meth) acrylate-based polymer is prepared from a reaction mixture comprising:
- at least one multifunctional polyester-containing (meth) acrylate;
- at least one polyester-containing (meth) acrylate oligomer;
- and an initiator, and is able to removably adhere to the anti-reflective, nanostructured surface of the optical construction;
- adhering the low tack adhesive layer of the tape to the anti-reflective, nanostructured surface coating on the second major surface of the optical construction to form an optical laminate;
- subjecting the optical laminate to a temperature of 150° C. for 1 hour under a pressure of 4.31 kiloPascals;
- and
- cleanly removing the tape from the anti-reflective, nanostructured surface coating on the second major surface of the optical construction.
Dependencies are inferred from the claim text.