Coating additive
AssigneesDow Global Technologies LLC, Rohm and Haas Company
InventorsLiqiang Fan, Rui Wang, Jianming Xu
Life of this patent
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Abstract
The present invention provides a coating additive copolymer comprising, as copolymerized units, by dry weight based on total dry weight of the copolymer, from 20% to 60%, at least one acetoacetoxy or acetoacetamide functional ethylenically unsaturated monomer, and from 40% to 80% at least one water soluble ethylenically unsaturated monomer. It further provides a coating formulation comprising higher than 0.04% by dry weight based on total dry weight of the coating formulation, the acetoacetoxy or acetoacetamide functional ethylenically unsaturated monomer.
Claims7
A coating formulation comprising a coating additive copolymer comprising, as copolymerized units, by dry weight based on total dry weight of the copolymer,
- from 20% to 60%, at least one acetoacetoxy or acetoacetamide functional ethylenically unsaturated monomer, and
- from 40% to 80% at least one water soluble ethylenically unsaturated monomer having the following structure:
- D-(CH2CH2O)h—(CH2CH(CH3)O)k-E
- wherein h is an integer of from 0 to 150;
- and k is an integer of from 0 to 30;
- wherein D is an ethylenically unsaturated group comprising methacrylate (CH2═C(CH3)CO2—), methacrylamide (CH2═C(CH3)CONH—), acrylate (CH2=CHCO2—), acrylamide (CH2=CHCONH—), vinyl ether (CH2═CH—O—), or allyl ether (CH2═CHCH2—O—);
- and
- wherein E is a capping group, and is selected from H, alkyl having 1 to 4 carbon atoms, and anionic salt groups comprising a lithium, sodium, potassium, or ammonium salt of phosphonate, phosphate, sulfate, or sulfonate;
- sodium vinylsulfonate;
- or sodium p-styrenesulfonate;
- wherein the coating formulation comprises, as copolymerized units, from 0.1% to 2% by dry weight based on total dry weight of the coating formulation, of the acetoacetoxy or acetoacetamide functional ethylenically unsaturated monomer.
Dependencies are inferred from the claim text.