Polymerizable composition comprising silsesquioxane compound having acrylic group
AssigneeNissan Chemical Industries, Ltd.
InventorsKei Yasui, Takehiro Nagasawa, Taku Kato, Keisuke Shuto
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Abstract
There is provided a polymerizable composition suitable to produce a molded product in which high refractive index is maintained, and dimensional change and a transmittance change further caused by a high-temperature heat history can be suppressed. A polymerizable composition comprising (a) 100 parts by mass of a specific reactive silsesquioxane compound and (b) 10 to 2,000 parts by mass of a specific fluorene compound, and a cured product obtained by curing the polymerizable composition, and a resin lens manufactured from the polymerizable composition.
Claims12
A polymerizable composition comprising:
- (a) 100 parts by mass of reactive silsesquioxane compound as a polycondensate of an alkoxy silicon compound A of Formula [1] with an alkoxy silicon compound B of Formula [2] in an amount by mole of 0 to 99 times the amount of the alkoxy silicon compound:
- R1—Si(OR2)3 [1]
- where R1 is a C1-10 alkyl group having at least one (meth)acryloyloxy group and R2 is a methyl group or an ethyl group,
- R3—Si(OR4)3 [2]
- where R3 is a C1-10 alkyl group, a C7-10 aralkyl group, or a C6-14 aryl group and R4 is a methyl group or an ethyl group;
- (b) 10 to 2,000 parts by mass of fluorene compound of Formula [3]:
- where R5 and R6 are each independently a hydrogen atom or a methyl group, L1 and L2 are each independently a phenylene group optionally having a substituent or a naphthalenediyl group optionally having a substituent, L3 and L4 are each independently a C1-6 alkylene group, and m and n are 0 or a positive integer with m+n satisfying 0 to 40;
- and
- (c) a chain transfer agent in an amount of 0.01 to 10 parts by mass relative to 100 parts by mass of the total amount of the components (a) and (b).
Dependencies are inferred from the claim text.