Hydrogenated block copolymer, polypropylene resin composition, and molding
AssigneeAsahi Kasei Kabushiki Kaisha
InventorsYasuhiro Kusanose, Hiroyuki Ichino, Masashi Yamamoto, Masahiro Fujiwara, Toshikazu Hoshina
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Abstract
The present invention provides a hydrogenated block copolymer containing, in the molecule thereof, a polymer block (C) having a conjugated diene compound as a main component, a polymer block (B) having a conjugated diene compound as a main component, and a polymer block (S) having a vinyl aromatic compound as a main component.
Claims14
A hydrogenated block copolymer comprising, in a molecule thereof, a polymer block (C) having a conjugated diene compound as a main component, a polymer block (B) having a conjugated diene compound as a main component, and a polymer block (S) having a vinyl aromatic compound as a main component, wherein:
- in the hydrogenated block copolymer, a content of the polymer block (C) is 1 to 20% by mass, a content of the polymer block (B) is 69 to 98% by mass, and a content of the polymer block (S) is 1 to 15% by mass;
- a vinyl bond content before hydrogenation of the polymer block (C) is 1 to 25 mol %, and a vinyl bond content before hydrogenation of the polymer block (B) is 60 to 100 mol %;
- a degree of hydrogenation of the hydrogenated block copolymer is 80 mol % or more;
- a tan δ peak obtained by a dynamic viscoelasticity measurement (1 Hz) of the hydrogenated block copolymer is in a range of higher than −45° C. and 10° C. or lower, a height of the tan δ peak is 1.0 or more, and a width at half height of the tan δ peak is 20° C. or lower;
- a value obtained from VH−VL is 10 mol % or less;
- and
- when the polymer block (B) is divided into a first region to a sixth region in order from a polymerization start side, each region having an equal mass, VH and VL represent a highest value and a lowest value, respectively, of vinyl bond contents before hydrogenation of the first region to the sixth region.
A polypropylene resin composition comprising 10 to 90% by mass of the hydrogenated block copolymer according to claim 1 and 10 to 90% by mass of a polypropylene resin, wherein
- in a wide angle X ray diffractometry of the polypropylene resin composition, an intensity ratio of diffraction peak intensity (I14) at a scattering angle (2θ) of 14° to diffraction peak intensity (I15) at a scattering angle (2θ) of 15°, I14/I15, is 0.1 or more and less than 1.4.
Dependencies are inferred from the claim text.