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US 10,703,688 B2Granted
Method for producing organic acids and organic acid degradation compounds from biomass
AssigneeGeorgia-Pacific Corporation
InventorsJohn Patrick Kelly, Michael Eugene Carroll, Paul Topping
Life of this patent
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Abstract
A method and integrated reactor system are provided for producing one or more organic acids, organic acid degradation compounds, and combinations thereof, from various types of biomass, including sludge from a pulp and paper mill.
Claims20
A process for producing one or more organic acids, comprising:
- contacting a lignocellulosic biomass comprising a six carbon chain sugar precursor with steam to heat the lignocellulosic biomass to a temperature of about 150° C. to about 250° C. within a tubular reactor with axial mixing to produce an at least partially hydrolyzed lignocellulosic biomass comprising a six carbon chain sugar;
- heating the at least partially hydrolyzed lignocellulosic biomass comprising the six carbon chain sugar to a temperature of about 150° C. to about 250° C. within a plug flow reactor to convert the six carbon chain sugar to a first product comprising a first organic acid;
- heating a sludge from a pulp and paper mill comprising an additional six carbon chain sugar to convert the additional six carbon chain sugar to a second product comprising a second organic acid;
- and
- mixing the first product and the second product to produce a combined product.
2 more elements
A process for producing levulinic acid, comprising:
- contacting a lignocellulosic biomass comprising a six carbon chain sugar precursor with steam to heat the lignocellulosic biomass to a temperature of about 170° C. to about 230° C. within a tubular reactor with axial mixing to produce an at least partially hydrolyzed lignocellulosic biomass comprising a six carbon chain sugar;
- contacting the at least partially hydrolyzed lignocellulosic biomass with a first mineral acid and heating the at least partially hydrolyzed lignocellulosic biomass to a temperature of about 150° C. to about 250° C. within a plug flow reactor to convert the six carbon chain sugar to a first product comprising levulinic acid and tar;
- heating a sludge from a pulp and paper mill comprising an additional six carbon chain sugar to convert the additional six carbon chain sugar to a second product comprising levulinic acid and tar;
- mixing the first product and the second product to produce a combined product;
- and
- separating the levulinic acid from the tar to produce a purified levulinic acid product.
3 more elements
A process for producing one or more organic acids, comprising:
- introducing a heated mixture comprising steam and a lignocellulosic biomass comprising a six carbon chain sugar precursor to a first reactor, wherein the first reactor comprises a tubular reactor with axial mixing;
- at least partially hydrolyzing the lignocellulosic biomass within the first reactor to produce an at least partially hydrolyzed lignocellulosic biomass comprising a six carbon chain sugar;
- introducing the at least partially hydrolyzed lignocellulosic biomass to a second reactor, wherein the second reactor comprises a plug flow reactor;
- heating the at least partially hydrolyzed lignocellulosic biomass within the second reactor to a temperature of about 150° C. to about 250° C. to produce a first product comprising a first organic acid;
- introducing a sludge from a pulp and paper mill comprising an additional six carbon chain sugar to a third reactor;
- and
- heating the sludge within the third reactor to a temperature of about 150° C. to about 250° C. to produce a second product comprising a second organic acid.
4 more elements
Dependencies are inferred from the claim text.