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US 10,702,625 B2Granted
Skin-adhesive item
AssigneeElkem Silicones France SAS
InventorsCaroline Moine, Maryline Quemin
Life of this patent
Estimating the term…
Abstract
Items that can adhere to the skin for medical or paramedical use are described. Also described, is a skin-adhesive item.
Claims33
A skin-adhesive item comprising:
- a support S which is a flexible polyurethane film having a top face S1 and a bottom face S2,
- at least one tie primer C1 applied to at least one part or to all of the top face S1 of the support S,
- at least one layer D1 comprising a silicone gel E obtained by crosslinking a crosslinkable silicone composition Y by means of a hydrosilylation reaction, which has been applied to the at least one tie primer C1 facing the support S, and
- optionally at least one protective layer F comprising of a peel-off protective material and applied to the at least one layer D1,
- wherein the at least one tie primer C1 comprises a silicone elastomer which is not a silicone gel and which is obtained by crosslinking a silicone composition X comprising:
- 1) at least one organopolysiloxane A comprising, per molecule, at least two vinyl radicals each bonded to a silicon atom and comprising:
- (i) at least two siloxy units of formula (A1):
- YaZbSiO(4−(a+b)/2 (A1)
- wherein:
- Y represents a C2 to C6 alkenyl group,
- Z represents a monovalent hydrocarbon-based group chosen from alkyl groups having from 1 to 8 carbon atoms inclusive, cycloalkyl groups, and aryl groups,
- a and b represent integers, a being 1, 2 or 3, b being 0, 1 or 2 and (a+b) being 1, 2 or 3;
- (ii) and optionally comprising other siloxy units of formula (A2):
- ZcSiO(4−c)/2 (A2)
- wherein:
- Z has the same meaning as above, and
- c represents an integer which is 0, 1, 2 or 3;
- 2) at least one organopolysiloxane B comprising, per molecule, at least three hydrogen atoms each bonded to a silicon atom and comprising:
- (i) at least three siloxy units of formula (B1):
- HZbSiO(3−b)/2 (B1)
- wherein:
- H is a hydrogen atom,
- Z represents a monovalent hydrocarbon-based group chosen from alkyl groups having from 1 to 8 carbon atoms inclusive, cycloalkyl groups, and aryl groups,
- b is 0, 1 or 2;
- (ii) and optionally comprising other siloxy units of formula (B2):
- ZcSiO(4−c)/2 (B2)
- wherein:
- Z has the same meaning as above, and
- c represents an integer which is 0, 1, 2, or 3;
- 3) at least one hydrosilylation catalyst C;
- 4) at least one hydrosilylation reaction inhibitor D;
- 5) optionally at least one stabilizing additive K;
- and
- 6) optionally at least one silicone resin M which has hydroxyl groups and is free of alkenyl or hydrosilyl SiH groups, and
- with the proviso that the amounts by weight of the organopolysiloxanes A and B are determined such that the RHalk=nH/tAlk ratio is 1.00≤RHalk≤4.5 with:
- nH=number of moles of hydrogen atom directly bonded to a silicon atom of the organopolysiloxane B, and
- tAlk=number of moles of alkenyl directly bonded to a silicon atom of the organopolysiloxane A.
34 more elements
Dependencies are inferred from the claim text.