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US 10,689,570 B2Granted
Silicate phosphors
AssigneeMerck Patent GmbH
InventorsAleksander Zych, Ralf Petry, Mathias Rapphahn, Ingo Koehler, Stefan Tews
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Abstract
The invention relates to pyrosilicate phosphors comprising a coating of aluminum oxide, to a process for the preparation of these compounds, and to the use thereof as conversion phosphors or in lamps.
Claims20
A compound of formula (1),
- (Ba2−a−b−c−dMaAbREcDd)(Mg1−e−f−g−jM′eA′fRE′gC′j)(Si2−h−iB′hC″i)(O7+m−k−lXkNl) Formula (1)
- where the following applies to the symbols and indices used:
- M is Ca, Sr, Zn or a mixture of these elements;
- A is Na, K, Rb or a mixture of these elements;
- RE is La, Y, Gd or a mixture of these elements;
- D is Eu2+, Mn2+, Yb2+, Sm2+ or a mixture of these elements;
- M′ is Zr, Hf or a mixture of these elements;
- A′ is Li, Na or a mixture of these elements;
- RE′ is Sc, Lu or a mixture of these elements;
- C′ is B, Al, Ga, In or a mixture of these elements;
- B′ is Ge, Sn or a mixture of these elements;
- C″ is B, Al, Ga, In or a mixture of these elements;
- X is F, Cl or a mixture of these elements;
- N is nitrogen;
- 0≤a≤1.0;
- 0≤b≤0.6;
- 0≤c≤0.6;
- 0<d≤2;
- 0≤e≤0.3;
- 0≤f≤0.3;
- 0≤g≤0.3;
- 0≤j≤0.6;
- 0≤h≤1.0;
- 0≤i≤0.6;
- 0≤k≤2.1;
- 0≤l≤2.1;
- −2.0≤m≤2.0;
- wherein at least one and a maximum of three of the indices b, c, e, f, g, h, i, j, k, and l is ≠0;
- and
- wherein the compound contains a coating of aluminum oxide which has been deposited by an ALD process.
27 more elements
Dependencies are inferred from the claim text.