Back to results
US 10,654,029 B2Granted
Bridged bi-aromatic ligands and olefin polymerization catalysts prepared therefrom
AssigneeUnivation Technologies, LLC
InventorsCatherine Anne Faler, C. Jeff Harlan
Life of this patent
Estimating the term…
Abstract
Disclosed are novel bridged bi-aromatic phenol ligands and transition metal catalyst compounds derived therefrom. Also disclosed are methods of making the ligands and transition metal compounds, and polymerization processes utilizing the transition metal compounds for the production of olefin polymers.
Claims18
A catalyst composition comprising one or more transition metal compounds comprising a bridged bi-aromatic phenol ligand of formula (I);
- wherein each of R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12 is independently selected from the group consisting of hydride, halide, optionally substituted hydrocarbyl, heteroatom-containing optionally substituted hydrocarbyl, alkoxy, aryloxy, silyl, boryl, dialkyl amino, alkylthio, arylthio and seleno;
- optionally two or more R groups can combine together into ring structures with such ring structures having from 3 to 100 non-hydrogen atoms in the ring;
- A is an optionally substituted divalent alkyl, alkenyl, alkynyl, heteroalkyl, heteroalkenyl, heteroalkynyl, carbocycle, heterocarbocycle, aryl, heteroaryl, or silyl;
- Y and Y′ are independently selected from O, S, NRa and PRa wherein Ra is optionally substituted hydrocarbyl;
- Ar is, independently, optionally substituted aryl or optionally substituted heteroaryl;
- and
- one or more activators.
4 more elements
Dependencies are inferred from the claim text.