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AssigneeAllnex Netherlands B.V.
InventorsRam Gupta, Lawrence Flood, Urvee Treasurer, Barry Lawless, Colin Brogan
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The invention relates to a coating composition comprising a reaction product UA of at least one multifunctional aldehyde A with at least one cyclic urea U, and a crosslinkable resin having at least one kind of functional groups selected from the group consisting of hydroxyl functional groups, acid functional groups, amide functional groups, amino functional groups, imino functional groups, mercaptan functional groups, phosphine functional groups, and carbamate functional groups, characterised in that the degree of etherification, measured as the ratio «(13 O—R)/«(U) of the amount of substance n(—O—R) of alkoxy groups as substituents of the aldehyde carbon atoms of the multifunctional aldehyde chemically bound in the reaction product UA to the amount of substance «(U) of cyclic urea U chemically bound in the reaction products, is less than 0.01 mol/mol, and to a process for the preparation of the reaction product UA.
A process for making a non-etherified reaction product UA of at least one multifunctional aldehyde A and at least one cyclic urea U, wherein the ratio of the amount of substance of aldehyde groups n(—CHO) in the multifunctional aldehyde A and the amount of substance of amide groups n(—CO—NH) in the cyclic urea U is 1.0 mol/mol≤n(—CHO)/n(—CO—NH)≤1.30 mol/mol, characterised in that the reaction of U and A is conducted in the presence of a solvent which does not have functional groups that are reactive with the said at least one multifunctional aldehyde A or the said at least one cyclic urea U, or the non-etherified reaction product UA, and that the degree of etherification, measured as the ratio n(—O—R)/n(U) of the amount of substance n(—O—R) of alkoxy groups as substituents of the aldehyde carbon atoms of the multifunctional aldehyde chemically bound in the reaction product UA to the amount of substance n(U) of cyclic urea U chemically bound in the reaction products, is less than 0.01 mol/mol.
A process for making a non-etherified reaction product UA of at least one multifunctional aldehyde A and at least one cyclic urea U, wherein the ratio of the amount of substance of aldehyde groups n(—CHO) in the multifunctional aldehyde A and the amount of substance of amide groups n(—CO—NH) in the cyclic urea U is 1.0 mol/mol≤n(—CHO)/n(—CO—NH)≤1.30 mol/mol, characterised in that the process comprises at least two steps, wherein in the first step the amount of multifunctional aldehyde A used is between 20% and 80% of the total amount, and that after the first step, in at least one further step, further quantities of multifunctional aldehyde A are added and reacted with the reaction mixture formed in the previous step, and that the degree of etherification, measured as the ratio n(—O—R)/n(U) of the amount of substance n(—O—R) of alkoxy groups as substituents of the aldehyde carbon atoms of the multifunctional aldehyde chemically bound in the reaction product UA to the amount of substance n(U) of cyclic urea U chemically bound in the reaction products, is less than 0.01 mol/mol.
Dependencies are inferred from the claim text.