Back to results
US 10,647,587 B2Granted
Process for the ammonia production
AssigneeCasale SA
InventorsErmanno Filippi, Raffaele Ostuni
Life of this patent
Estimating the term…
Abstract
Process and plant for the synthesis of ammonia from a hydrocarbon feedstock, comprising: primary reforming with steam and air-fired secondary reforming wherein primary reforming is performed at a temperature and pressure of at least 790° C. and 50 bar, and secondary reforming is carried out substantially in absence of excess air, the so obtained make-up synthesis gas having a H2 to N2 molar ratio in the range 2.5 to 3.
Claims12
A process for the synthesis of ammonia from a hydrocarbon feedstock, the process comprising:
- a step of primary reforming of said hydrocarbon feedstock with steam obtaining a first reformed gas,
- a step of air-fired secondary reforming of said first reformed gas, obtaining a raw gas product,
- purification of said raw gas product obtaining a make-up synthesis gas,
- conversion of said make-up synthesis gas into ammonia in a synthesis loop,
- wherein:
- said primary reforming is performed at a temperature of at least 790° C. and pressure of at least 50 bar;
- said step of secondary reforming is carried out substantially in absence of excess air relative to the stoichiometric amount;
- said make-up synthesis gas has a H2 to N2 molar ratio of 2.5 or greater but less than 3 and the process includes extraction from said loop of a purge stream, separation of a hydrogen-containing stream from said purge stream and addition of said hydrogen-containing stream to said make-up gas in order to adjust said H2 to N2 ratio.
5 more elements
Dependencies are inferred from the claim text.