Use of PEBA having long blocks for the manufacture of all or part of a catheter
AssigneeArkema France
InventorsRené-Paul Eustache, Frédéric Malet, Eric Gamache, Alejandra Reyna-Valencia, Damien Rauline
Life of this patent
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Abstract
A copolymer containing polyether blocks and polyamide blocks for manufacturing an inflatable catheter element, such as a catheter balloon, with improved bursting strength, in which said copolymer has the following characteristics: number-average molecular mass of the PE blocks greater than 500 g/mol, and number-average molecular mass of the PA blocks greater than 10 000 g/mol.
Claims3
A process for manufacturing a burst-proof catheter balloon, said process comprising:
- a) a step of providing a copolymer containing polyether blocks and polyamide blocks in which said copolymer has the following characteristics:
- 1) number-average molecular mass of the polyether blocks greater than 500 g/mol,
- 2) number-average molecular mass of the polyamide blocks greater than 13,000 g/mol, and
- 3) the copolymer comprises polyether blocks composed of a majority of PTMG monomer units,
- 4) a Shore hardness of greater than 72;
- b) an optional step of mixing said copolymer with at least one other polymer and/or at least one additive, so as to manufacture a composition comprising:
- 1) from 30% to 100% by weight of a said copolymer containing polyether blocks and polyamide blocks
- 2) from 0 to 70% by weight of at least one other polymer chosen from polyamides, TPU, COPE, PVC, ABS, PS, PET, PETE, PVDF, ETFE, Polyimide, PEEK, PEKK, and silicone,
- 3) from 0 to 40% of at least one additive, relative to the total weight of the composition;
- c) a step of processing said copolymer or said composition at a temperature within the range from 200 to 300° C.;
- d) a step of forming the balloon at a temperature below the Tm (melting point) of the copolymer;
- e) a step of recovering the balloon.
A method comprising manufacturing an inflatable catheter balloon with improved bursting strength with a powder or granule composition, wherein said powder or granule composition comprises:
- 1) from 30% to 100% by weight of a copolymer containing polyether blocks and polyamide blocks in which said copolymer has the following characteristics:
- a) number-average molecular mass of the polyether blocks greater than 500 g/mol,
- b) number-average molecular mass of the polyamide blocks greater than 13,000 g/mol, and
- c) the copolymer comprises polyether blocks composed of a majority of PTMG monomer units,
- d) a Shore hardness of greater than 72;
- 2) from 0 to 70% by weight of at least one other polymer chosen from polyamides, TPU, COPE, PVC, ABS, PS, PET, PETE, PVDF, ETFE, Polyimide, PEEK, PEKK, and silicone,
- 3) from 0 to 40% of at least one additive,
- relative to the total weight of the composition.
Dependencies are inferred from the claim text.