Semiconductor nanoparticle, dispersion liquid, film, and method of producing semiconductor nanoparticle
AssigneeFUJIFILM Corporation
InventorTsutomu Sasaki
Life of this patent
Estimating the term…
Abstract
An object of the present invention is to provide a semiconductor nanoparticle having high emission efficiency and excellent durability; a method of producing the same; and a dispersion liquid and a film obtained by using a semiconductor nanoparticle. The semiconductor nanoparticle of the present invention is a semiconductor nanoparticle in which oxygen, zinc, and sulfur are detected by X-ray photoelectron spectroscopy analysis and a peak (ICH3) which is derived from a hydrocarbon group and present in a range of 2800 cm−1 to 3000 cm−1 and a peak (ICOO) which is derived from COO− and present in a range of 1400 cm−1 to 1600 cm−1 are detected by Fourier transform infrared spectroscopy analysis.
Claims28
A semiconductor nanoparticle,
- wherein oxygen, zinc, and sulfur are detected by X-ray photoelectron spectroscopy analysis, and
- a peak (ICH3) which is derived from a hydrocarbon group and present in a range of 2800 cm−1 to 3000 cm−1 and a peak (ICOO) which is derived from COO− and present in a range of 1400 cm−1 to 1600 cm−1 are detected by Fourier transform infrared spectroscopy analysis,
- wherein a molar ratio of oxygen to sulfur which is acquired by X-ray photoelectron spectroscopy analysis satisfies Formula (1), and
- a molar ratio of oxygen to zinc which is acquired by X-ray photoelectron spectroscopy analysis satisfies Formula (2),
- 0.20≤O/S≤0.80 (1)
- 0.30≤O/Zn≤1.10 (2)
- wherein two or more kinds of ligands are coordinated,
- wherein both of a ligand A which is represented by Formula (A) and contains a carboxyl group and a ligand B which is represented by Formula (B) and contains a mercapto group are coordinated,
- R1—COOH (A)
- R2—SH (B)
- where R1 and R2 in Formulae (A) and (B) each independently represent an organic group, and
- wherein both of R1 and R2 in Formulae (A) and (B) represent a linear aliphatic hydrocarbon group.
Dependencies are inferred from the claim text.