Compositions and methods to produce alkoxylated triazine-arlhydroxy-aldehyde condensates
AssigneeHexion Inc.
InventorsGanapathy S. Viswanathan, Anthony Maiorana, Stephan Schröter, Pravin Kukkala
Life of this patent
Estimating the term…
Abstract
The embodiments described herein generally relate to methods and chemical compositions of triazine-arylhydroxy-aldehyde condensates. In one embodiment, a triazine-arylhydroxy-aldehyde condensate is reacted with at alkoxylation agent to form alkoxylated triazine-arylhydroxy-aldehyde condensates.
Claims20
A condensation product of a reaction mixture comprising:
- a 1,3,5-triazine-arylhydroxy-aldehyde condensate and alkoxylation by an alkoxylation agent comprising:
- an alkylene oxide;
- and an optional alkylene carbonate;
- and an optional catalyst, wherein the alkylene oxide is an epoxy functional compound and wherein the 1,3,5-triazine moiety of the 1,3,5-triazine-arylhydroxy-aldehyde condensate comprises at least one optionally substituted amino group.
An alkoxylated triazine-arylhydroxy-aldehyde condensate compound having a structure of:
- wherein R6 is Formula II or Formula III, and wherein R7 is a hydrogen atom, Formula II, or Formula IV;
- wherein R8 and R9 are each independently a hydrogen atom, an alkyl group with 1 to 10 carbon atoms, a vinyl group, a phenyl group, a hydroxyphenyl group, —NH(Formula IV), —N(Formula IV)2, —NH(Formula II), —N(Formula II)(Formula IV), —N(Formula II)2, —NH(Formula III), —N(Formula III)(Formula IV), —N(Formula III)2, NH(Formula V), —N(Formula IV)(Formula V), —N(Formula V)2, or —NH2;
- wherein R1 and R2 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, a vinyl group, or an alkyl group with 1 to 4 carbon atoms containing a hydroxyl group;
- wherein R10 is a hydrogen atom, an alkyl group with 1 to 10 carbon atoms, an alkyl group with 1 to 10 carbon atoms containing a hydroxyl group, a phenyl group, a vinyl group, a propenyl group, a hydroxyl containing phenyl group, a pyrrole group, or a (uranyl group;
- wherein R11 and R12 are each independently a hydrogen atom, an alkyl group with 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, a phenyl group, a hydroxybenzene group, or an alkyl group with 1 to 10 carbon atoms with at least one carbon substituted with i) a hydroxyl group, ii) a hydroxybenzene group, or iii) a phenyl group;
- or wherein R11 and R12 jointly form a common aromatic ring with or without a hydroxyl group;
- wherein R13 and R14 are each independently a hydrogen atom, an alkyl group with 1 to 10 carbon atoms, a vinyl group, a phenyl group, a hydroxyphenyl group, —NH(Formula IV), —N(Formula IV)2, —NH(Formula V), —N((Formula IV)(Formula V)), —N(Formula V)2, or —NH2;
- wherein R15, R16, and R17 are each independently a hydrogen atom, an alkyl group with 1 to 10 carbon atoms, a vinyl group, a phenyl group, a hydroxyphenyl group, —NH(Formula IV), —N(Formula IV)2, —NH(Formula V), —N(Formula IV)(Formula V), —N(Formula V)2, or —NH2;
- wherein each m is independently from 1 to 10, each n is independently from 0 to 10,
- wherein each x is independently from 1 to 20, and each x′ is independently from 1 to 20 when an alkoxylation agent is an alkylene oxide or wherein each x is independently from 1 to 20, and each x′ is independently from 1 to 20 with the average of all x and x′ is greater than 2 when the alkoxylation agent is a combination of an alkylene oxide and an alkylene carbonate,
- and wherein monomers depicted by m and n are arranged in any order, combination, or sub-combination.
A process comprising:
- alkoxylating a 1, 3, 5-triazine-arylhydroxy-aldehyde condensate by reacting with at least one alkylene oxide, alone or in combination with an alkylene carbonate, optionally in the presence of a catalyst;
- and forming an alkoxylated triazine-arylhydroxy-aldehyde condensate composition, wherein the alkylene oxide is an epoxy functional compound and wherein the 1,3,5-triazine moiety of the 1,3,5-triazine-arylhydroxy-aldehyde condensate comprises at least one optionally substituted amino group.
A condensation product of a reaction mixture comprising:
- a 1,2,3-triazine-arylhydroxy-aldehyde condensate and alkoxylation by an alkoxylation agent comprising:
- an alkylene oxide;
- and an optional alkylene carbonate;
- and an optional catalyst, wherein the alkylene oxide is an epoxy functional compound and wherein the 1,2,3-triazine moiety of the 1,2,3-triazine-arylhydroxy-aldehyde condensate comprises at least one optionally substituted amino group.
A condensation product of a reaction mixture comprising:
- a 1,2,4-triazine-arylhydroxy-aldehyde condensate and alkoxylation by an alkoxylation agent comprising:
- an alkylene oxide;
- and an optional alkylene carbonate;
- and an optional catalyst, wherein the alkylene oxide is an epoxy functional compound and wherein the 1,2,4-triazine moiety of the 1,2,4-triazine-arylhydroxy-aldehyde condensate comprises at least one optionally substituted amino group.
Dependencies are inferred from the claim text.