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US 10,633,491 B2Granted
Radically polymerizable compound
AssigneeMuhlbauer Technology GmbH
InventorsStephan Neffgen, Olav-Sven Becker
Life of this patent
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Abstract
The invention provides a radically polymerizable compound wherein an acid group is joined via a spacer group to a polyethyleneimine group. The polyethyleneimine group has at least one radically polymerizable group in the side chain and/or terminally. The invention relates further to a process for preparing such compounds by cationic polymerization of oxazolines, to the use of such compounds as constituents of a dental material, and to a dental material comprising the compounds of the invention.
Claims16
A radically polymerizable compound of the formula I:
- (SG)xA((PEI)TG)m
- where
- SG=—COOR1, —SO3R1, —OPO3R12, or —PO3R12;
- R1=independently at each occurrence H, C1-C7 alkyl, or monovalent cation;
- x=1-60;
- A:
- hydrocarbon group having 1 to 30 carbon atoms and possibly containing silicon, halogen, nitrogen, phosphorus, oxygen, and sulfur;
- SK═H, C1-C20 alkyl, aryl, alkyl-aryl, —(CO)NR3R4, —(CS)NR3R4, —(CO)OR3, —(CO)R3, or —(SO2)R3;
- R3, R4=independently at each occurrence H, alkyl, aryl and/or alkyl-aryl, which may contain halogen, nitrogen, phosphorus, oxygen, and sulfur, or alkenyl;
- n=2-100;
- TG=H, —NR6R7, —OR6, —SR6, cycloalkenes, —CR6R7R8, —OCOR9, or —NR6COR9;
- R6, R7, R8═H, C1 to C20 alkyl, aryl and/or alkyl-aryl, which may contain halogen, nitrogen, phosphorus, oxygen, and sulfur;
- a radically polymerizable group which may contain halogen, nitrogen, phosphorus, oxygen, and sulfur;
- where R6 and R7, with inclusion of the nitrogen atom, may form a ring having 5 to 7 ring atoms and possibly containing heteroatoms;
- R9=alkyl, aryl, alkyl-aryl, or alkenyl;
- where PEI or TG comprises at least one radically polymerizable group;
- m=1, 2, or 3.
14 more elements
Dependencies are inferred from the claim text.