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US 10,597,816 B2Granted
Fluorine-containing water-repellent composition
AssigneeArchroma IP GmbH
InventorsWolfgang Knaup, Waltraud Gasafi-Martin
Life of this patent
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Abstract
Composition, comprising at least components (A) and (B) and optionally at least one of components (C) to (E): (A) a polyacrylate obtained in the polymerisation of monomers (M1) CH2═CR3COO—R1 with (M2) CH2═CR3COO—R2 and optionally (M3) CH2═CR6COO—Y—RF (M4) CH2═CR3—X—R4; (B) a wax; (C) a blocked isocyanate; (D) an organic polysiloxane; (E) a melamine resin.
Claims20
A composition, comprising components (A) and (B) and optionally at least one of components (C) to (E):
- (A) a polyacrylate obtained in the polymerisation of monomers consisting of
- (M1) CH2═CR3COO—R1
- (M2) CH2═CR3COO—R2
- (M3) CH2═CR6COO—Y—RF and optionally
- (M4) CH2═CR3—X—R4;
- (B) a wax;
- (C) a blocked isocyanate;
- (D) an organic polysiloxane;
- (E) a melamine resin;
- wherein
- R1 is an alcohol moiety in (meth)acrylate monomer (M1) containing from 1 to 8 carbon atoms;
- R2 is an alcohol moiety in (meth)acrylate monomer (M2) containing from 9 to 40 carbon atoms;
- RF—Y is an alcohol moiety in (meth)acrylate monomer (M3), wherein
- Y is —(CH2)m—, wherein m is an integer in a range of from 1 to 10;
- and
- RF is CxF2x+1, wherein x is an integer in a range of from 1 to 12;
- R6 is selected from the group consisting of H, CH3, Cl, and F;
- R3 in monomer (M1), (M2) and (M4) is independently selected from the group consisting of H, CH3, and C2H5;
- X in monomer (M4) is COO or CONH;
- R4 is glycidyl or CH2(CH2)n—OR5, wherein n is an integer in a range of from 1 to 10 and R5 is H or a residue containing from 1 to 6 carbon atoms;
- and wherein the composition comprises water and/or an organic solvent.
18 more elements
A composition comprising components (A) and (B) and optionally at least one of components (C) and (E):
- (A) a polyacrylate obtained in the polymerisation of monomers
- (M1) CH2═CR3COO—R1
- (M2) CH2═CR3COO—R2
- (M3) CH2═CR6COO—Y—RF and optionally
- (M4) CH2═CR3—X—R4;
- (B) a wax;
- (C) a blocked isocyanate;
- (D) an organic polysiloxane;
- (E) a melamine resin;
- wherein
- R1 is an alcohol moiety in (meth)acrylate monomer (M1) containing from 1 to 8 carbon atoms;
- R2 is an alcohol moiety in (meth)acrylate monomer (M2) containing from 9 to 40 carbon atoms;
- RF—Y is an alcohol moiety in (meth)acrylate monomer (M3), wherein
- Y is —(CH2)m—, wherein m is an integer in a range of from 1 to 10;
- and
- RF is CXF2X+1, wherein x is an integer in a range of from 1 to 12;
- R6 is selected from the group consisting of H, CH3, Cl, and F;
- R3 in monomer (M1), (M2) and (M4) is independently selected from the group consisting of H, CH3, and C2H5;
- X in monomer (M4) is COO or CONH;
- R4 is glycidyl or CH2(CH2)n—OR5, wherein n is an integer in a range of from 1 to 10 and R5 is H or a residue containing from 1 to 6 carbon atoms;
- and wherein the composition comprises water and/or an organic solvent,
- wherein the composition comprises from
- 5 to 90% by weight of (A);
- 5 to 90% by weight of (B);
- 0 to 40% by weight of a blocked isocyanate (C);
- 0 to 40% by weight of an organic polysiloxane (D);
- 0 to 40% by weight of a melamine resin (E);
- 0.1-90% by weight of water and/or the organic solvent;
- based on a total amount of the composition (=100% by weight),
- wherein (D) is present.
27 more elements
Dependencies are inferred from the claim text.