Nonaqueous electrolytic solution for electric double layer capacitors
AssigneeOtsuka Chemical Co., Ltd.
InventorsYoshihisa Tokumaru, Yoshihiro Okada, Taiji Nakagawa, Shoji Hiketa, Koichi Sorajo
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Abstract
The present invention provides a nonaqueous electrolytic solution that provides an electric double layer capacitor having excellent durability. The nonaqueous electrolytic solution of the present invention is a nonaqueous electrolytic solution for electric double layer capacitors prepared by dissolving a quaternary ammonium salt as an electrolyte in a nonaqueous solvent, and the nonaqueous electrolytic solution has an alkali metal cation concentration of 0.1 to 30 ppm.
Claims6
A nonaqueous electrolytic solution for electric double layer capacitors prepared by dissolving a quaternary ammonium salt represented by formula (I):
- Q+X− (I),
- wherein Q+ represents a quaternary ammonium cation comprising pyrrolidinium, and X− represents a counter ion selected from the group consisting of PF6−, BF4−, AsF6−, N(CF3SO3)2−, SbF6−, and RfSO3−, wherein Rf is a fluoroalkyl group having 1 to 8 carbon atoms, as an electrolyte in a nonaqueous solvent,
- wherein:
- the quaternary ammonium salt excludes spiro quaternary ammonium tetrafluoroborate,
- the nonaqueous solvent is at least one solvent selected from the group consisting of propylene carbonate, ethylene carbonate, butylene carbonate, sulfolane, methylsulfolane, dimethyl carbonate, ethyl methyl carbonate, diethyl carbonate, γ-butyrolactone and mixtures thereof, and
- an alkali metal cation concentration is more than 10 ppm and not more than 30 ppm.
Dependencies are inferred from the claim text.