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US 10,591,761 B2Granted
Flexible plastic substrate and display device including same
AssigneesSamsung Electronics Co., Ltd., Samsung SDI Co., Ltd.
InventorsSang Soo Jee, Sun Jin Song, Chanjae Ahn, Sungwon Choi
Life of this patent
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Abstract
A flexible plastic substrate includes a film including a poly(amide-imide) copolymer; and a hard coating layer disposed on a first surface of the film, wherein the hard coating layer includes a crosslinked siloxane copolymer, and wherein the flexible plastic substrate has pencil hardness of greater than or equal to 2H under a vertical load of 1 kilogram according to ASTM D3363, a total light transmittance of greater than or equal to about 89% in a wavelength region of 350 nanometers to 750 nanometers.
Claims19
A flexible plastic substrate comprising
- a film comprising a poly(amide-imide) copolymer;
- and
- a hard coating layer disposed on a first surface of the film,
- wherein the hard coating layer comprises a crosslinked siloxane copolymer wherein the crosslinked siloxane copolymer comprises a cured product of a siloxane copolymer represented by at least one of Chemical Formula 1, Chemical Formula 2, or Chemical Formula 3:
- (R1SiO3/2)x(R2R3SiO2/2)y Chemical Formula 1
- wherein, in Chemical Formula 1,
- R1 is a cross-linkable functional group or a hydrocarbyl group substituted with a cross-linkable functional group,
- R2 and R3 are each independently hydrogen, a cross-linkable functional group, a hydrocarbyl group substituted with a cross-linkable functional group, a substituted or unsubstituted C1 to C20 alkyl group, or a substituted or unsubstituted C5 to C20 cycloalkyl group, provided that at least one of R2 and R3 is a substituted or unsubstituted C1 to C20 alkyl group, and
- 0<x<1, 0<y<1, and x+y=1,
- (R1SiO3/2)x(R4SiO3/2)z Chemical Formula 2
- wherein, in Chemical Formula 2,
- R1 is a cross-linkable functional group or a hydrocarbyl group substituted with a cross-linkable functional group;
- R4 is an ultraviolet light absorbing functional group or a C1 to C20 hydrocarbyl group substituted with an ultraviolet light absorbing functional group;
- and
- 0<x<1, 0<z<1, and x+z=1,
- (R1SiO3/2)x(R2R3SiO2/2)y(R4SiO3/2)z Chemical Formula 3
- wherein in Chemical Formula 3,
- R1 is a cross-linkable functional group or a hydrocarbyl group substituted with a cross-linkable functional group;
- R2 and R3 are each independently hydrogen, a cross-linkable functional group, a hydrocarbyl group substituted with a cross-linkable functional group, a substituted or unsubstituted C1 to C20 alkyl group, or a substituted or unsubstituted C5 to C20 cycloalkyl group, provided that at least one of R2 and R3 is a substituted or unsubstituted C1 to C20 alkyl group;
- R4 is an ultraviolet light absorbing functional group or a C1 to C20 hydrocarbyl group substituted with an ultraviolet light absorbing functional group;
- and
- 0<x<1, 0<y<1, 0<z<1, and x+y+z=1, and
- wherein the flexible plastic substrate has
- a pencil hardness of greater than or equal to 2H under a vertical load of 1 kilogram according to ASTM D3363,
- a total light transmittance of greater than or equal to about 89% in a wavelength region of 350 nanometers to 750 nanometers.
22 more elements
Dependencies are inferred from the claim text.