Accelerators for two part curable compositions

A two part curable composition comprising:

• Part A:
• a cure accelerator consisting of one or more derivatives of benzoyl thiourea or thiourethane within structure I or IA below:
• wherein Z is O or N—R, wherein R is a member selected from the group consisting of hydrogen, alkyl, alkenyl, hydroxyalkyl, hydroxyalkenyl, alkylene (meth)acrylate, carbonyl, carboxyl, or sulfonato, R′ is a member selected from the group consisting of hydrogen, alkyl, alkenyl, aryl, hydroxyalkyl, hydroxyalkenyl, alkylene (meth)acrylate, carbonyl, carboxyl, or sulfonate, or R or R′ is a direct bond attaching to the phenyl ring;
• wherein X is optional, but when X is present, X is a member selected from the group consisting of alkenyl, cycloalkyl, hydroxyalkyl, hydroxyalkenyl, amino, alkylene- or alkenylene-ether, alkylene (meth)acrylate, carbonyl, carboxyl, nitroso, sulfonate, hydroxyl or haloalkyl;
• and Y is a member selected from the group consisting of —SO2NH—, —CONH—, —NH—, and —PO(NHCONHCSNH2)NH—;
• and n is 0 or 1 and m is 1 or 2, or
• wherein R and R′ are independent members selected from the group consisting of alkenyl, aryl, hydroxyalkyl, hydroxyalkenyl, alkylene (meth)acrylate, carbonyl, carboxyl, or sulfonato, or R and R′ taken together form a carbocyclic or hetero atom-containing ring, or R′ is a direct bond attaching to the phenyl ring;
• wherein X is optional, but when X is present, X is a member selected from the group consisting of alkenyl, cycloalkyl, hydroxyalkyl, hydroxyalkenyl, amino, alkylene or alkenylene-ether, alkylene (meth)acrylate, carbonyl, carboxyl, sulfonate, hydroxyl or haloalkyl;
• and Y is a member selected from a group consisting of —SO2NH—, —CONH—, —NH—, and —PO(NHCONHCSNH2)NH—;
• and n is 0 or 1 and m is 1 or 2;
• and
• Part B:
• an oxidant selected from the group consisting of cumene hydroperoxide, para-menthane hydroperoxide, t-amyl hydroperoxide, 1,1,3,3-tetramethylbutyl hydroperoxide, t-butyl hydroperoxide, t-butyl perbenzoate, benzoyl peroxide, dibenzoyl peroxide, 1,3-bis(t-butylperoxyisopropyl)benzene, diacetyl peroxide, butyl 4,4-bis(t-butylperoxy)valerate, p-chlorobenzoyl peroxide, t-butyl cumyl peroxide, t-butyl perbenzoate, di-t-butyl peroxide, dicumyl peroxide, 2,5-dimethyl-2,5-di-t-butylperoxyhexane, 2,5-dimethyl-2,5-di-t-butyl-peroxyhex-3-yne, 4-methyl-2,2-di-t-butylperoxypentane, and combinations thereof, wherein at least one of Part A or Part B further comprises a (meth)acrylate component.