High solids, low viscosity urethane-linkage containing latex and method of production thereof
AssigneeArkema Inc.
InventorsWayne Devonport, Wu Wenjun, Kyu-Jun Kim
Life of this patent
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Abstract
A latex comprising a urethane linkage and having a high solids content and a low viscosity is described herein. Also described is a process for making the urethane linkage-containing latex wherein urethane linkage formation and emulsion polymerization take place in the same processing step.
Claims17
A latex comprising polymer having a urethane linkage, wherein said urethane-containing latex is formed during a singe processing step that includes emulsion polymerization and urethane linkage formation in the presence of a surfactant or emulsifying agent by polymerizing isocyanate with a monomer mixture, said monomer mixture including at least one isocyanate reactive monomer (A) and at least one additional monomer (B), said monomers (A) and (B) selected from the group consisting of alkyl(meth)acrylate monomers, vinyl esters of linear or branched carboxyli acids, styrene or styrene derivatives, hydroxyl-substituted alkyl esters of (meth)acrylic acids, wet adhesion monomers, carbonyl containing monomers, ionic monomers, phosphorus containing monomers, sulfur containing monomers and a combination thereof, wherein the isocyanate and the monomer mixture are combined prior to polymerization and not after, and wherein the solids content of the latex is greater than or equal to 47%, the viscosity is less than 3000 centipoise, the particle size is less than or equal to 500 nm, and the coagulum content as measured by weighing undispersed polymer in water after drying at 110° C. for 1 hour is less than 2%.
An emulsion polymerization method for producing a latex containing a urethane linkage comprising polymerizing by emulsion polymerization an isocyanate and a monomer mixture comprising no polymers, said monomers including an isocyanate reactive monomer and at least one additional monomer, to produce the latex, wherein the monomer mixture and the isocyanate are combined prior to polymerization and not after, emulsion polymerization and urethane linkage formation occurring substantially simultaneously during a single processing step.
Dependencies are inferred from the claim text.