Hydrobromination method
AssigneeArkema France
InventorsBernard Berthe, Bernard Pees, Philippe Annoot, Jean-Luc Dubois, Ornella Zovi
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Abstract
A process for synthesizing a product of formula Br—(CH2)n—R by hydrobromination, by reacting: a reagent of formula (I) R1-CH═CH—R2 in which R1 and R2, identical or different, are chosen from H or an alkyl radical comprising 1 to 30 carbon atoms, which is saturated or unsaturated, linear or branched, functionalized or non-functionalized, with a molar excess of HBr relative to the reagent of formula (I), in the presence of a radical initiator, and optionally in the presence of at least one solvent, said process including a step A of mixing at least reagent I and the HBr, each of the latter arriving in the form of a flow of liquid into a mixing device dA.
Claims24
A process for synthesizing a product of formula R1-CHBr—CH2—R2 by hydrobromination by reacting:
- a) a reagent of formula (I) R1-CH═CH—R2 in which R1 and R2, which may be identical or different, are chosen from H or an alkyl radical comprising from 1 to 30 carbon atoms, which is saturated or unsaturated, linear or branched, and functionalized or non-functionalized,
- b) with a molar excess of HBr relative to the reagent of formula (I),
- in the presence of a radical initiator,
- and optionally in the presence of at least one solvent,
- said process comprising a step A of mixing at least the reagent I and the HBr, each of the latter arriving respectively in the form of a liquid stream in a mixing device dA,
- wherein a turbulent flow system prevails, so as to reach, at the end of this step A, a degree of conversion included in the range of from 10% to 100%, and
- wherein the process further comprises a step B of spontaneous continuation of the reaction in a device dB in which a transient or laminar flow system prevails, so as to reach, at the end of this step, a degree of conversion of greater than 90%,
- wherein the residence times in the devices dA and dB are such that the degree of conversion at the end of step A is included in the range of from 10% to 90%, while the degree of conversion at the end of step B is included in the range of from 90% to 100%.
Dependencies are inferred from the claim text.