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US 10,589,215 B2Granted
Production of biomethane using multiple types of membrane
AssigneeAir Liquide Advanced Technologies U.S. LLC
InventorsYong Ding, Michael J. Mitariten
Life of this patent
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Abstract
The invention relates to a process for recovering methane from digester biogas or landfill gas. More specifically, the invention pertains to a method for producing biomethane that removes impurities from a compressed digester biogas with staged membrane modules of at least two different types, to produce a biomethane having at least 94% CH4, below 3% of CO2, and below 4 ppm of H2S.
Claims18
A method for producing biomethane, comprising:
- compressing a biogas feed in a compressor to produce a compressed feed stream;
- passing said compressed feed stream to a first separation stage comprising at least one polymeric gas separation membrane to retain a first gas mixture comprising at least 60% of methane, and to permeate a first low-quality gas mixture comprising impurities present in said biogas feed stream and less than 20% of methane, said biogas feed comprising 40-75% of methane, 20-55% of carbon dioxide, up to 5,000 ppm of hydrogen sulfide (“H2S”), an amount of siloxanes, an amount of water, and up to 2,000 ppm of volatile organic compounds (“VOC's”), said at least one membrane of said first separation stage being selective for each of H2S, siloxanes, and VOC's over CH4,
- sending a stream of said first gas mixture into a second separation stage comprising at least one polymeric gas separation membrane, to retain a second gas mixture containing at least 94% of methane, and to permeate a second permeate gas mixture comprising impurities present in said biogas feed stream and less than 70% of methane;
- recycling a stream of said second permeate gas mixture to said compressor;
- and
- withdrawing said second gas mixture from said second separation stage as biomethane, wherein said membrane of said first separation stage is substantially different from said membrane of said second separation stage, and said method excludes the use of regenerable adsorbent, said biomethane containing at least 94% methane, below 3% of CO2, below 4 ppm of H2S, below 100 ppm of VOC's, and below 0.01 wt. % of H2O.
3 more elements
Dependencies are inferred from the claim text.