Polymerizable liquid crystal compound, composition, liquid crystal polymerization film-kind thereof and use thereof
AssigneesJnc Corporation, Jnc Petrochemical Corporation
InventorDaisuke Ootsuki
Life of this patent
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Abstract
An object is to provide a polymerizable liquid crystal compound, a polymerizable liquid crystal composition containing the compound and liquid crystal polymerization film-kind capable of controlling chromatic dispersion characteristics and having low positive chromatic dispersion characteristics. An aspect can be exemplified in which the polymerizable liquid crystal compound is represented by formula (1): in which, in formula (1), G is a group composed of a quinoline skeleton, an isoquinoline skeleton, a quinoxaline skeleton or a quinazoline skeleton, A1 is 1,4-phenylene or 1,4-cyclohexylene, Z1 is a connecting group, m is an integer from 0 to 3, and R1 is a group containing a polymerizable group.
Claims12
A polymerizable liquid crystal compound, represented by formula (1):
- wherein, in formula (1),
- A1 is independently 1,4-phenylene, 1,4-cyclohexylene, 1-cyclohexene-1,4-ylene, 2-cyclohexene-1,4-ylene, pyridine-2,5-diyl or naphthalene-2,6-diyl, and in the 1,4-phenylene or the naphthalene-2,6-diyl, at least one hydrogen may be replaced by fluorine, chlorine, trifluoromethyl, alkyl having 1 to 5 carbons, alkoxy having 1 to 5 carbons, alkoxycarbonyl having 1 to 5 carbons or alkanoyl having 1 to 5 carbons,
- Z1 is independently a single bond, —OCH2—, —CH2O—, —COO—, —OCO—, —CF2O—, —OCF2—, —CH2CH2—, —CF2CF2—, —OCH2CH2O—, —CH═CHCOO—, —OCOCH═CH—, —CH2CH2COO—, —OCOCH2CH2—, —CH2CH2OCO—, —COOCH2CH2—, —CH═CH—, —N═CH—, —CH═N—, —N═C(CH3)—, —C(CH3)═N—, —N═N— or —C≡C—,
- m is each independently an integer from 0 to 3, in which at least one m is not 0,
- G is a divalent organic group that comprises a quinoline skeleton, an isoquinoline skeleton, benzoquinoline skeleton, a quinoxaline skeleton, a benzoquinoxaline skeleton or a quinazoline skeleton, wherein G has 10 to 24τ-electrons, and
- R1 is independently hydrogen, fluorine, chlorine, trifluoromethyl, trifluoromethoxy, cyano, alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, alkylester having 1 to 12 carbons or a group represented by formula (2), in which at least one R1 is a group represented by formula (2);
- —Y-Q1-PG (2)
- wherein, in formula (2),
- Y1 is a single bond, —O—, —COO—, —OCO— or —OCOO—,
- Q1 is a single bond or alkylene having 1 to 20 carbons, and in the alkylene, at least one —CH2— may be replaced by —O—, —COO—, —OCO—, —CH═CH— or C≡C—, and
- PG is a polymerizable group represented by any one of formula (PG-1) to formula (PG-9):
- wherein, in formula (PG-1) to formula (PG-9), RPG is independently hydrogen, halogen, methyl, ethyl or trifluoromethyl.
Dependencies are inferred from the claim text.