Lithium ion secondary battery
AssigneeSekisui Chemical Co., Ltd.
InventorRie Teranishi
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Abstract
A lithium ion secondary battery 10 includes at least one cell obtained by laminating a positive electrode 1, an electrolyte layer 2, and a negative electrode 3 in this order. The electrolyte layer 2 contains a fluoride. The negative electrode 3 has a negative electrode active material layer containing a silicon compound. At least one of the negative electrodes 3 has a mass ratio of fluorine/silicon (F/Si ratio) of 1.0 or less on a surface of the negative electrode active material layer.
Claims3
A lithium ion secondary battery comprising an electrode laminate having a plurality of cells, each of which is independently a laminate of a positive electrode, a separator, and a negative electrode in this order, wherein
- the negative electrode in each laminate has a negative electrode active material layer containing a silicon compound,
- each of the negative electrodes has a mass ratio of fluorine/silicon (F/Si ratio) ranging from more than 0 to 1.0 on a surface of the negative electrode active material layer, and
- a value obtained by dividing a maximum value by a minimum value among F/Si ratios of the negative electrodes included in each of the cells is 1.04 to 2.32.
A method of manufacturing a lithium ion secondary battery comprising an electrode laminate having a plurality of cells, each of which is independently a laminate of a positive electrode, a separator, and a negative electrode which are laminated in this order, wherein
- the negative electrode in each laminate has a negative electrode active material layer containing a silicon compound,
- each of the negative electrodes has a mass ratio of fluorine/silicon (F/Si ratio) ranging from more than 0 to 1.0 on a surface of the negative electrode active material layer, and
- a value obtained by dividing a maximum value by a minimum value among F/Si ratios of the negative electrodes included in each of the cells is 1.04 to 2.32,
- the method comprising:
- a lithium doping treatment which is performed by immersing the electrode laminate and a lithium metal foil in an electrolytic solution containing a fluoride at a temperature in a range of 0-20° C.
Dependencies are inferred from the claim text.