Method for obtaining sugar derivatives
AssigneeAnnikki GmbH
InventorsDörthe Hendrike Wirtz, Bernd Mayer
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Abstract
A process for converting a sugar from a hemicellulose-containing material into the form of a compound having at least one ionic binding site, which is characterized in that the hemicellulose-containing material is hydrolyzed enzymatically or non-enzymatically and the obtained hydrolysate is subjected to a conversion involving at least one enzymatic step, wherein sugars are released and the released sugars are converted into compounds having at least one ionic binding site, and the use of such a process.
Claims17
A process for converting a sugar from a hemicellulose-containing material into a compound having at least one ionic binding site, the process comprising:
- providing a hemicellulose-containing material from an annual plant including arabinose and xylose;
- hydrolysing the hemicellulose-containing material enzymatically or non-enzymatically to obtain a hydrolysate, the hydrolysate including arabinose and xylose as released sugars;
- subjecting the obtained hydrolysate to a conversion in a reaction mixture involving at least one enzymatic step, the conversion comprising converting at least a portion of the released sugars into a compound having at least one ionic binding site, by:
- oxidizing the arabinose in a first redox reaction by means of a first oxidoreductase into arabino-γ-lactone, and
- hydrolysing said arabino-γ-lactone to arabonic acid,
- wherein the conversion involves redox cofactors comprising at least one of NADH/NAD+ or NADPH/NADP+, at least one of NAD+ or NADP+ being reduced to NADH or NADPH as part of the first redox reaction involving the first oxidoreductase and the arabinose,
- and at least one of NADH or NADPH being oxidized to NAD+ or NADP+ in a second redox reaction carried out in the reaction mixture by means of a xylose reductase, the xylose reductase being different from the first oxidoreductase, and wherein the xylose reductase reduces at least a portion of the released xylose.
A process for converting a sugar from a hemicellulose-containing material into a compound having at least one ionic binding site in a single reaction mixture process, the process comprising:
- providing a hemicellulose-containing material from an annual plant including xylose and arabinose;
- hydrolysing the hemicellulose-containing material to obtain a hydrolysate, the hydrolysate including released arabinose and xylose sugars;
- without prior isolation of the released arabinose and xylose sugars, converting at least a portion of the released arabinose into a compound having at least one ionic binding site, the conversion comprising:
- oxidizing the arabinose into arabino-γ-lactone using an arabinose dehydrogenase and one or more redox cofactors;
- and
- hydrolysing the arabino-γ-lactone to arabonic acid using at least one of an arabinolactonase or an alkaline hydrolysis process,
- wherein the one or more redox cofactors include at least one of NADH/NAD+ or NADPH/NADP+, the one or more redox cofactors being reduced in the single reaction mixture during the oxidation of the arabinose, and the one or more redox cofactors being oxidized in the single reaction mixture through action of a xylose reductase and in combination with a reducible organic compound.
Dependencies are inferred from the claim text.