Organically modified metal nanoparticles
AssigneeSuper Nano Design Co., Ltd.
InventorTadafumi Ajiri
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AssigneeSuper Nano Design Co., Ltd.
InventorTadafumi Ajiri
Estimating the term…
A technique for bonding an organic group with the surface of fine particles such as nanoparticles through strong linkage is provided, whereas such fine particles are attracting attention as materials essential for development of high-tech products because of various unique excellent characteristics and functions thereof. Organically modified metal oxide fine particles can be obtained by adapting high-temperature, high-pressure water as a reaction field to bond an organic matter with the surface of metal oxide fine particles through strong linkage. The use of the same condition enables not only the formation of metal oxide fine particles but also the organic modification of the formed fine particles. The resulting organically modified metal oxide fine particles exhibit excellent properties, characteristics and functions.
An organically modified metal oxide nanoparticle wherein a hydrocarbon group is directly bonded to a surface of each metal oxide nanoparticle through a linkage from the hydrocarbon group selected from the group consisting of an ether bond, an ester bond, a bond through an N atom, a bond through an S atom, a metal-C— bond, a metal-C═ bond, and a metal-(C═O)— bond, wherein said hydrocarbon group is a hydrocarbon group with a chain having 1, 2 or 3 carbon atoms, or a long-chain hydrocarbon group with a chain having 4 or more carbon atoms, or said hydrocarbon group is a substituted or unsubstituted straight-chain or branched-chain alkyl group, and said metal oxide is an oxide of a metal element selected from group consisting of an element of group VIII, an element of group IB, an element of group IIB, an element of group IIIB, an element of group IVB, an element of group VB, an element of group VIB, and an element of groups IA to VIIA, in the long-period periodic table, provided that TiO2 is excluded from said metal oxides, wherein the organically modified metal oxide nanoparticle is produced by reacting an organic modifying agent (organic modifier) with the surface of a metal oxide nanoparticle in the reaction field of water at a pressure of 10 MPa or above and at a temperature of 250° C. or above to form said organically modified metal oxide nanoparticle wherein the hydrocarbon group is covalently bonded to the surface of said metal oxide nanoparticle.
An organically modified metal oxide nanoparticle wherein a hydrocarbon group is directly bonded to a surface of each metal oxide nanoparticle through a linkage from the hydrocarbon selected from the group consisting of a an ether bond, an ester bond, a bond through an N atom, a bond through an S atom, a metal-C— bond, a metal-C═ bond, and a metal-(C═O)— bond, wherein said hydrocarbon group is a hydrocarbon group with a chain having 1, 2 or 3 carbon atoms, or a long-chain hydrocarbon group with a chain having 4 or more carbon atoms, or said hydrocarbon group is a substituted or unsubstituted straight-chain or branched-chain alkyl group, and the metal element in said metal oxide is selected from the group consisting of Zr, Nb, Y, Eu, Mg, Ce, Ba, Mn, Co, Ni, Ru, Rh, Pd, Os, Ir, Zn, Cd, Hg, B, Ga, In, Tl, Sn, Pb, As, Sb, Bi, Te and Po, wherein the organically modified metal oxide nanoparticle is produced by reacting an organic modifying agent (organic modifier with the surface of a metal oxide nanoparticle in the reaction field of water at a pressure of 10 MPa or above and at a temperature of 250° C. or above to form said organically modified metal oxide nanoparticle wherein the hydrocarbon group is covalently bonded to the surface of said metal oxide nanoparticle.
Dependencies are inferred from the claim text.