Polymer compound, intermediate composition, negative electrode, electrical storage device, slurry for negative electrode, method for producing polymer compound, and method for producing negative electrode
AssigneeKabushiki Kaisha Toyota Jidoshokki
InventorsTakeshi Kondo, Yusuke Sugiyama, Nobuhiro Goda
Life of this patent
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Abstract
A polymer compound is formed by condensing a polyacrylic acid having some of carboxyl groups converted into a lithium salt with a polyfunctional amine represented by the following general formula (1). A chain structure constituted by the polyacrylic acid has free carboxyl groups and carboxyl groups converted into a lithium salt. Y is a straight-chain alkyl group having 1 to 4 carbon atoms, a phenylene group, or an oxygen atom. R1 and R2 are each independently one or more hydrogen atoms, a methyl group, an ethyl group, a trifluoromethyl group, or a methoxy group.
Claims12
A polymer compound to be used as a binder for a negative electrode of a power storage device, wherein
- the polymer compound is formed by condensing a polyacrylic acid having some of carboxyl groups converted into a lithium salt with a polyfunctional amine represented by the following general formula (1),
- a chain structure constituted by the polyacrylic acid has free carboxyl groups and carboxyl groups converted into a lithium salt:
- where
- Y is a straight-chain alkyl group having 1 to 4 carbon atoms, a phenylene group, or an oxygen atom, and
- R1 and R2 are each independently one or more hydrogen atoms, a methyl group, an ethyl group, a trifluoromethyl group, or a methoxy group.
A polymer compound to be used as a binder for a negative electrode of a power storage device, wherein
- the polymer compound has a chain structure constituted by a polyacrylic acid, and a crosslinked structure connecting carboxyl groups in the chain structure or between the chain structures with each other,
- the crosslinked structure is at least one crosslinked structure selected from the following general formulae (2) to (4), and
- the chain structure has free carboxyl groups and carboxyl groups converted into a lithium salt
- where PAA denotes the chain structure constituted by the polyacrylic acid converted into a lithium salt;
- X is a structure represented by the following general formula (5):
- where
- Y is a straight-chain alkyl group having 1 to 4 carbon atoms, a phenylene group, or an oxygen atom, and
- R1 and R2 are each independently a hydrogen atom, a methyl group, a trifluoromethyl group, or a methoxy group.
An intermediate composition of a polymer compound to be used as a binder for a negative electrode of a power storage device, wherein
- the intermediate composition contains a polyacrylic acid having some of carboxyl groups converted into a lithium salt, a polyfunctional amine represented by the following general formula (1), and a mixed solvent of a nonaqueous solvent with water,
- the polyacrylic acid and the polyfunctional amine are dissolved in the mixed solvent:
- where
- Y is a straight-chain alkyl group having 1 to 4 carbon atoms, a phenylene group or an oxygen atom, and
- R1 and R2 are each independently one or more hydrogen atoms, a methyl group, an ethyl group, a trifluoromethyl group, or a methoxy group.
Dependencies are inferred from the claim text.