Hydrogenated syndiotactic norbornene-based ring-opening polymer
AssigneeZeon Corporation
InventorsShigetaka Hayano, Richard Royce Schrock, Benjamin Autenrieth
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Abstract
A hydrogenated norbornene-based ring-opening polymer having a syndiotacticity ((racemo diads)/(meso diads+racemo diads)×100) of more than 90% is disclosed. A method for producing the same is also disclosed. It is thus possible to provide a hydrogenated highly syndiotactic norbornene-based ring-opening polymer that is formed of a single material, and exhibits high solvent resistance, and a method for producing the same.
Claims2
A hydrogenated norbornene-based ring-opening polymer obtained by hydrogenating of carbon-carbon double bonds of a norbornene-based ring-opening polymer obtained by ring-opening polymerization of a norbornene monomer represented by the formula (3), having a syndiotacticity ((racemo diads)/(meso diads+racemo diads)×100) of more than 95%
- wherein m is 1 or 2, and Ra and Rb are independently selected from the group consisting of a hydrogen atom;
- a substituted alkyl group having 1 to 12 carbon atoms substituted with substituted or unsubstituted aryl groups having 6 to 12 carbon atoms, alkoxy groups having 1 to 12 carbon atoms, haloalkyl groups having 1 to 12 carbon atoms, haloalkoxy groups having 1 to 12 carbon atoms, an amino group, monosubstituted amino groups, disubstituted amino group and an imino group;
- an unsubstituted alkyl group having 1 to 12 carbon atoms;
- a substituted or unsubstituted cycloalkyl group having 3 to 20 carbon atoms;
- and a substituted or unsubstituted aryl group having 6 to 12 carbon atoms.
Dependencies are inferred from the claim text.