Polymer based memristors
AssigneeThe University of Western Ontario
InventorsJoe B. Gilroy, Giovanni Fanchini, Joseph A. Paquette, Sabastine C. Ezugwu
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AssigneeThe University of Western Ontario
InventorsJoe B. Gilroy, Giovanni Fanchini, Joseph A. Paquette, Sabastine C. Ezugwu
Estimating the term…
Disclosed herein are redox-active 6-oxoverdazyl polymers having structures (S1) and (S2) synthesized via ring-opening metathesis polymerization (ROMP) and their solution, bulk, and thin-film properties investigated. Detailed studies of the ROMP method employed confirmed that stable radical polymers with controlled molecular weights and narrow molecular weight distributions (Ð<1.2) were produced. Thermal gravimetric analysis of a representative example of the title polymers demonstrated stability up to 190° C., while differential scanning calorimetry studies revealed a glass transition temperature of 152° C. An ultrathin memristor device was produced using these polymers, namely a 10 nm homogeneous thin film of poly-[1,5-diisopropyl-3-(cis-5-norbornene-exo-2,3-dicarboxiimide)-6-oxoverdazyl] (P6OV), a poly-radical with three tunable charge states per each radical monomer: positive, neutral and negative.
A memristor, comprising:
A memristor, comprising:
Dependencies are inferred from the claim text.