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US 10,527,758 B2Granted
Composition for forming dye type polarizer and dye type polarizer
AssigneeLG Chem, Ltd.
InventorsDong Woo Yoo, Sung-Ho Chun, Kyung Chang Seo, Hyeong Bin Jang
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Abstract
The present invention relates to a composition for forming a dye-type polarizer, which can be used to provide a dye-type polarizer showing excellent degree of polarization, heat resistance and dichroic ratio, and to a dye-type polarizer. The composition for forming a dye-type polarizer includes a curable anisotropic dye having a particular chemical structure; and an orientation auxiliary agent having a predetermined chemical structure.
Claims16
A composition for forming a dye-type polarizer, comprising:
- a curable anisotropic dye of the following Chemical Formula 1;
- and
- an orientation auxiliary agent of the following Chemical Formula 2 or a radical polymer thereof,
- wherein a weight ratio between the curable anisotropic dye and the orientation auxiliary agent is 1:95 to 25:50, and
- wherein the curable anisotropic dye and the orientation auxiliary agent forms a crosslinking structure in the dye-type polarizer,
- wherein the dye-type polarizer comprising a dye layer including a cured product of the composition for forming a dye-type polarizer, wherein the dye layer has a dichroic ratio of 10 or higher, and a degree of polarization of the dye-type polarizer is 90 or higher, and a reduction rate of degree of polarization after heat treatment at 80° C. for 48 hours is 10% or less:
- wherein n is an integer of 2 to 5, in which two or more of a repeating unit of —(A1-N═N)— are the same as or different from each other, respectively,
- at least one of Q1 and Q2 is a curable unsaturated functional group, and the other is hydrogen, alkyl having 1 to 20 carbon atoms, alkoxy having 1 to 20 carbon atoms, alkylester having 1 to 20 carbon atoms, or amine,
- A1 and A2 are the same as or different from each other, and are substituted or unsubstituted arylene having 6 to 40 carbon atoms, or substituted or unsubstituted heteroarylene having 4 to 30 carbon atoms,
- B1 and B2 are the same as or different from each other, and are a divalent functional group in a combination of one or more selected from the group consisting of a single bond, —(C═O)O—, —O(C═O)—, substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 40 carbon atoms, substituted or unsubstituted heteroarylene having 4 to 30 carbon atoms, substituted or unsubstituted alkyleneoxide having 1 to 20 carbon atoms, —O—, —S—, —NR1— and —PR1—, and
- R1 is hydrogen or alkyl having 1 to 20 carbon atoms,
- Q3-B3-A3-N═N-A4-B4-Q4 [Chemical Formula 2]
- wherein at least one of Q3 and Q4 is a curable unsaturated functional group, and the other is hydrogen, alkyl having 1 to 20 carbon atoms, alkoxy having 1 to 20 carbon atoms, alkylester having 1 to 20 carbon atoms, —CN, —NO2, halogen, or amine unsubstituted or substituted with 1 or 2 of alkyl having 1 to 6 carbon atoms,
- A3 and A4 are the same as or different from each other, and are substituted or unsubstituted arylene having 6 to 40 carbon atoms, or substituted or unsubstituted heteroarylene having 4 to 30 carbon atoms,
- B3 and B4 are the same as or different from each other, and are a divalent functional group in a combination of one or more selected from the group consisting of a single bond, —(C═O)O—, —O(C═O)—, substituted or unsubstituted alkylene having 1 to 20 carbon atoms, substituted or unsubstituted arylene having 6 to 40 carbon atoms, substituted or unsubstituted heteroarylene having 4 to 30 carbon atoms, substituted or unsubstituted alkyleneoxide having 1 to 20 carbon atoms, —O—, —S—, —NR2— and —PR2—, and
- R2 is hydrogen or alkyl having 1 to 20 carbon atoms.
13 more elements
Dependencies are inferred from the claim text.