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US 10,519,337 B2Granted
Coating compositions for packaging articles such as food and beverage containers
AssigneeThe Sherwin-Williams Company
InventorsSebastien Gibanel, Benoit Prouvost
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Abstract
An article, comprising a food or beverage container (20), or a portion thereof, that includes a metal substrate (30, 32) and a coating (34) disposed on at least a portion of the metal substrate (30, 32). The coating (34) is preferably formed from a coating composition that comprises an emulsion polymerized latex having a first-stage emulsion polymerized copolymer and a second-stage emulsion polymerized copolymer.
Claims21
A method of making an inside spray coating composition for food or beverage containers, the method comprising:
- emulsion polymerizing first-stage monomers in an aqueous carrier to produce a first-stage copolymer comprising water-dispersing groups;
- emulsion polymerizing second-stage monomers, wherein at least 5% by weight of the second-stage monomers are chemically different from the first-stage monomers, in the presence of the first-stage copolymer to form a second-stage copolymer, wherein the second-stage copolymer is chemically different from the first-stage copolymer, and wherein the second-stage copolymer comprises a curing group configured to react with the first-stage copolymer during a curing step;
- and
- formulating the coating composition for a spray coating application, wherein the coating composition is substantially free of one or more, or all, of structural units derived from each of (meth)acrylamide-type monomers and bisphenol A, and wherein the coating composition spray-applied onto an interior of a 12 ounce two-piece drawn and ironed aluminum beverage can and cured at 188° C. to 210° C. (measured at the can dome) for 60 seconds provides an inside spray beverage can coating with an average film thickness of about 0.7 mg/in2 to about 4.0 mg/in2, and the can coating exhibits a global extraction result of less than 50 ppm as measured according to the extraction procedure in 21 C.F.R. § 175.300, paragraphs (d)-(e).
1 more element
Dependencies are inferred from the claim text.