Monolithic separation membrane structure and method of manufacture thereof
AssigneeNGK Insulators, Ltd.
InventorsMakoto Teranishi, Makiko Ichikawa, Hideyuki Suzuki
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Abstract
A monolithic separation membrane structure comprises a substrate, a first support layer and a separation membrane. The substrate is composed of a porous material and including a plurality of through holes. The first support layer is formed on an inner surface of the plurality of through holes. The separation membrane arranged in the first support layer. The first support layer includes an aggregate material having alumina as a main component, an inorganic binder have titania as a main component, and a sintering additive having at least one of silica and magnesia as a main component.
Claims5
A method for manufacturing a monolithic separation membrane structure comprising:
- forming a green body for a substrate, the substrate composed of a porous material and including a plurality of through holes;
- firing the green body for the substrate;
- forming a green body for a first support layer on an inner surface of the plurality of through holes by use of a material that contains an aggregate material having alumina as a main component, an inorganic binder having titania as a main component, and a sintering additive having silica as a main component;
- firing the green body for the first support layer;
- forming a green body for a second support layer on an inner surface of the first support layer by use of a material that contains alumina as a main component, and a sintering additive having at least one of silica and magnesia as a main component;
- firing the green body for the second support layer;
- and
- arranging a separation membrane on an inner side of the second support layer,
- wherein the silica concentration in the first support layer is at least 0.25 wt % to no more than 6 wt %, and the magnesia concentration in the second support layer is at least 0.01 wt % to no more than 40 wt %.
A monolithic separation membrane structure comprising:
- a substrate composed of a porous material and including a plurality of through holes;
- a first support layer formed on a surface of the plurality of through holes;
- a second support layer formed on an inner surface of the first support layer;
- and
- a separation membrane formed on an inner surface of the second support layer;
- wherein the first support layer includes alumina aggregate, titania inorganic binder and silica sintering additive, and the second support layer includes alumina and at least one of silica and magnesia,
- wherein the silica concentration in the first support layer is at least 0.25 wt % to no more than 6 wt %, and when the second support layer includes magnesia as a sintering additive, a magnesia concentration in the second support layer is at least 0.01 wt % to no more than 40 wt %.
A monolithic separation membrane structure comprising:
- a substrate composed of a porous material and including a plurality of through holes;
- a first support layer formed on a surface of the plurality of through holes;
- a second support layer formed on an inner surface of the first support layer;
- and
- a separation membrane formed on an inner surface of the second support layer;
- wherein the first support layer includes alumina aggregate, titania inorganic binder and silica sintering additive, and the second support layer includes alumina and at least one of silica and magnesia,
- wherein the silica concentration in the first support layer is at least 0.25 wt % to no more than 6 wt %, and when the second support layer includes both silica and magnesia as a sintering additive, a silica concentration in the second support layer is at least 0.01 wt % to no more than 10 wt %, and a magnesia concentration in the second support layer is at least 0.01 wt % to no more than 10 wt %.
Dependencies are inferred from the claim text.