# US 10,502,792 B2 · Method for evaluating insulating performance of separator for electrochemical device

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- Number: US 10,502,792 B2
- Document ID: US10502792B2
- Status: Granted
- Kind: B2
- Application number: 16/285,926
- Filed: 2019-02-26
- Published: 2019-08-29
- Granted: 2019-12-10
- Earliest claimed: 2018-02-26
- Assignees: LG Chem, Ltd.
- Applicants: LG Chem, Ltd.
- Inventors: Hyun-Kyung Shin; Dong-Wook Sung; Sang-Joon Lee
- Web page: https://patentgrep.com/patent/US10502792B2

## CPC

- G01R 31/1263: {of solid or fluid materials, e.g. insulation films, bulk material; of semiconductors or LV electronic components or parts; of cable, line or wire insulation}
- G01R 31/389: Measuring internal impedance, internal conductance or related variables
- G01R 31/378: specially adapted for the type of battery or accumulator
- H01M 10/4285: {Testing apparatus}
- H01M 10/484: {for measuring electrolyte level, electrolyte density or electrolyte conductivity}
- H01M 10/488: {Cells or batteries combined with indicating means for external visualization of the condition, e.g. by change of colour or of light density}
- G01R 19/16571: {comparing AC or DC current with one threshold, e.g. load current, over-current, surge current or fault current (G01R19/16514, G01R19/16519, G01R19/16528, G01R19/16533, G01R19/1659 take precedence; measuring currents by using elements sensitive to the magnetic field generated G01R15/14; measuring earth resistance G01R27/18; testing for leakage or short circuits in electrical apparatus G01R31/52)}
- G01R 31/16: Construction of testing vessels; Electrodes therefor
- G01R 31/20: Preparation of articles or specimens to facilitate testing
- G01R 31/3865: {related to manufacture, e.g. testing after manufacture}
- H01M 10/052: Li-accumulators
- Y02E 60/10: Energy storage using batteries
- G01R: MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES (indicating correct tuning of resonant circuits H03J3/12)
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A method for evaluating the insulating performance of a separator using an insulating performance evaluation system according to an exemplary embodiment of the present disclosure includes: preparing a measurement subject wherein a metal contact layer is interposed between two sheets of separator so as to form a plurality of local contacts with the surface of the separator; sandwiching the measurement subject between an upper jig and a lower jig; applying a voltage the magnitude of which varies with time between the upper jig and the lower jig using a voltage application unit; receiving a current measurement value flowing between the upper jig and the lower jig as an input from a current measurement unit; and determining the voltage value at which the current measurement value is equal to or greater than a preset critical value as a dielectric breakdown voltage, by a control unit.

## Claims

### Claim 1

A method for evaluating the insulating performance of a separator for use in blocking contact between positive and negative electrodes in an electrochemical device, comprising:
preparing a measurement subject having the separator to be evaluated therein, wherein the measurement subject includes a metal contact layer is interposed between two sheets of the separator so as to form a plurality of local contacts with surfaces of each of the two sheets of the separator, and wherein the surface area of the metal contact layer is less than the total surface area of the separator such that the metal contact layer is spaced apart from the edges of each of the two sheets of the separator;
sandwiching the measurement subject between an upper jig and a lower jig;
applying a voltage the magnitude of which varies with time between the upper jig and the lower jig using a voltage application unit;
receiving a current measurement value flowing between the upper jig and the lower jig as an input from a current measurement unit; and
determining the voltage value at which the current measurement value is equal to or greater than a preset critical value as a dielectric breakdown voltage, by a control unit.

### Claim 2 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, wherein the metal contact layer of the measurement subject includes a metal mesh, and wherein the preparing the measurement subject comprises:
inserting the metal mesh between two sheets of the separator; and
forming the plurality of local contacts between the separator and the metal mesh by thermally compressing the two sheets of the separator having the metal mesh inserted.

### Claim 3 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, wherein the metal contact layer of the measurement subject includes a metal particle layer comprising a plurality of metal particles, and wherein the preparing the measurement subject comprises:
scattering the plurality of metal particles onto one of the two sheets of the separator; and
forming the plurality of local contacts between the separator and the plurality of metal particles by positioning the other separator on the separator onto which the plurality of metal particles have been scattered.

### Claim 4 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, wherein the metal contact layer of the measurement subject includes a metal particle layer comprising a plurality of metal particles and an organic binder binding them, and wherein the preparing the measurement subject comprises:
preparing a slurry comprising the plurality of metal particles, the organic binder and a volatile solvent;
forming a metal contact layer by coating the slurry onto one of the two sheets of the separator and drying the same; and
forming the plurality of local contacts between the separator and the plurality of metal particles by positioning the other separator on the separator onto which the metal contact layer has been formed and then thermally compressing the two sheets of the separator.

### Claim 5 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, wherein the area of the metal contact layer is 60-70% of the total area of the separator, and the metal contact layer is formed with a predetermined spacing from the edge of the separator.

### Claim 6 (depends on 2)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 2, wherein the metal mesh has a diameter of a weft and a warp of 15-2000 μm and a gap between the weft and the warp of 15-10000 μm.

### Claim 7 (depends on 3)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 3, wherein the metal particle comprised in the metal particle layer has a size of 15-1000 μm.

### Claim 8 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, wherein, in the determining the voltage value, when the current measurement value is equal to or greater than the critical value for a preset reference time, the control unit determines the voltage value measured immediately after the reference time has passed as a dielectric breakdown voltage.

### Claim 9 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, which further comprises, after the applying the voltage and before the receiving the current measurement value, interposing metal foils between the measurement subject and the upper jig and between the measurement subject and the lower jig.

### Claim 10 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, wherein, in the applying the voltage, the measurement subject is compressed by applying pressure to the upper jig and the lower jig.

### Claim 11 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, wherein, in the applying the voltage, at least one of the upper jig and the lower jig is heated.

### Claim 12 (depends on 10)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 10, wherein the pressure applied the upper jig and the lower jig is 5 kPa to 30 MPa.

### Claim 13 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, which further comprises recording the determined dielectric breakdown voltage in a storage unit.

### Claim 14 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, which further comprises displaying the determined dielectric breakdown voltage by a display unit.

### Claim 15 (depends on 1)

The method for evaluating the insulating performance of a separator for an electrochemical device according to claim 1, wherein the voltage is a DC voltage or a pulse voltage the magnitude of which increases with time.