# US 10,502,367 B2 · Gas storage unit and associated structure and system > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 10,502,367 B2 - Document ID: US10502367B2 - Status: Granted - Kind: B2 - Application number: 14/419,649 - Filed: 2013-08-09 - Published: 2015-07-30 - Granted: 2019-12-10 - Earliest claimed: 2012-08-09 - Assignees: Aaqius & Aaqius SA - Applicants: Aaqius & Aaqius SA - Inventors: Jean-Baptiste Dementhon; Michael Francis Levy - Web page: https://patentgrep.com/patent/US10502367B2 ## CPC - F17C 11/00: Use of gas-solvents or gas-sorbents in vessels {(absorbing compositions for acetylene C10L3/04; absorbing compositions for hydrogen C01B3/0005)} - F01N 3/206: {Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents} - F01N 3/2066: {Selective catalytic reduction [SCR]} - F01N 13/16: Selection of particular materials - F17C 13/004: {for large storage vessels not under pressure (F17C13/008 and F17C13/02 - F17C13/12 take precedence)} - F01N 3/208: {Control of selective catalytic reduction [SCR], e.g. by adjusting the dosing of reducing agent} - F01N 2610/02: the substance being ammonia or urea - F01N 2610/06: the substance being in the gaseous form - F01N 2610/1406: Storage means for substances, e.g. tanks or reservoirs - F01N 2610/1413: Inlet and filling arrangements therefore - F01N 2610/1453: Sprayers or atomisers; Arrangement thereof in the exhaust apparatus - Y02T 10/12: Improving ICE efficiencies - F17C: VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES (storing fluids in natural or artificial cavities or chambers in the earth B65G5/00; construction or assembling of bulk storage containers employing civil-engineering techniques E04H7/00; variable-capacity gas-holders F17B; liquefaction or refrigeration machines, plants, or systems F25) - F01N: GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES (arrangements in connection with gas exhaust of propulsion units in vehicles B60K13/00; combustion-air intake silencers specially adapted for, or arranged on, internal-combustion engines F02M35/00; protecting against, or damping, noise in general G10K11/16) - Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION ## Abstract Unit for storing gas by absorption or adsorption, comprising a chamber containing a storage element (702, 704) that stores gas by absorption or adsorption, characterized in that it further comprises a compressible element (712) also provided within the chamber and kept in contact with the storage element (702, 704) and designed to deform under the action of loads applied by the storage element (702, 704) upon variations in volume of the storage element (702, 704) during phases of storing gas and releasing gas from storage, so as to limit the loads applied to the chamber. ## Claims ### Claim 1 A storage unit for storing gas by absorption or adsorption comprising: a container including a gas storage element; a compressible element disposed within the container and maintained in contact with the gas storage element, the compressible element adapted to deform under an action of forces exerted by the gas storage element during volume variations of the gas storage element during phases for storing and discharging gas, so as to limit forces applied on the container by said compressible element by compressing in a direction corresponding to a direction of said action of forces; an alternation of layers including a layer of the gas storage element and at least one layer of the compressible element; wherein each layer of the gas storage element forms a rigid wafer or disc, and wherein the compressible element includes a metal plate. ### Claim 2 (depends on 1) The storage unit according to claim 1, wherein the gas storage element is in a compressed powdery form. ### Claim 3 (depends on 1) The storage unit according to claim 1, wherein the compressible element comprises a porous medium. ### Claim 4 (depends on 1) The storage unit according to claim 1, including a series of gas storage elements separated one from the other with compressible elements. ### Claim 5 (depends on 1) The storage unit according to claim 1, including a first combination of the gas storage element, integrated into the compressible element so as to be surrounded by the compressible element. ### Claim 6 (depends on 5) The storage unit according to claim 5, including a second combination of the compressible element integrated into the gas storage element so as to be surrounded by the gas storage element. ### Claim 7 (depends on 6) The storage unit according to claim 6, including an alternation of first combination(s) and of second combination(s). ### Claim 8 (depends on 1) The storage unit according to claim 1, wherein the compressible element includes two portions, at least one portion being maintained bearing against the gas storage element, both portions being interconnected through an elastic mechanical element. ### Claim 9 (depends on 8) The storage unit according to claim 8, wherein the elastic mechanical element includes a spring. ### Claim 10 (depends on 1) A selective catalytic reduction system for exhaust gases of an internal combustion engine, wherein the system includes a storage unit for storing gas according to claim 1 and a module for injecting gas into the exhaust gases. ### Claim 11 (depends on 1) The storage unit according to claim 1, wherein the alternation of layers forms a stack of wafers or discs. ### Claim 12 (depends on 1) The storage unit according to claim 1, wherein during filling with gas, each gas storage element layer increases in volume and each layer of the compressible element is subject to forces which deform each layer of the compressible element. ### Claim 13 (depends on 1) The storage unit according to claim 1, wherein a play exists between an inner wall of the container and each layer of the compressible element so that each layer of the compressible element may thus deform so as to occupy a peripheral volume resulting from the play. ### Claim 14 (depends on 13) The storage unit according to claim 13, wherein the at least one layer of the compressible element may thus deform until the at least one layer of the compressible element forms a contact with the inner wall of the container in a play area. ### Claim 15 (depends on 13) The storage unit according to claim 13, wherein a thickness of each layer of the compressible element may decrease and a diameter of each layer of the compressible element increases without any change in density. ### Claim 16 (depends on 13) The storage unit according to claim 13, wherein the play between an edge of at least one layer of the compressible element and the inner wall of the container, is between 2% and 30%, of a transverse diameter of the at least one layer of the compressible element when the gas storage element is empty. ### Claim 17 (depends on 13) The storage unit according to claim 13, wherein the play between an edge of at least one layer of the compressible element and the inner wall of the container, is between 5% and 16%, of a transverse diameter of the at least one layer of the compressible element when the gas storage element is empty. ### Claim 18 (depends on 12) The storage unit according to claim 12. wherein the compressible element includes a second metal plate. ### Claim 19 (depends on 12) The storage unit according to claim 12, wherein the storage unit is dimensioned so that said deformation does not cause a change in density of the compressible element, as long as a free space in the container allows a change in shape of the compressible element at constant density. ### Claim 20 A storage unit for storing gas by absorption or adsorption comprising: a container including a gas storage element; a compressible element disposed within the container and maintained in contact with the gas storage element, the compressible element adapted to deform under an action of forces exerted by the gas storage element during volume variations of the gas storage element during phases for storing and discharging gas, so as to limit forces applied on the container by said compressible element by compressing in a direction corresponding to a direction of said action of forces; an alternation of layers including a layer of the gas storage element and at least one layer of the compressible element; wherein each layer of the gas storage element forms a rigid wafer or disc, wherein the compressible element includes a porous matrix of expanded natural graphite. ### Claim 21 (depends on 20) The storage unit according to claim 20, wherein expanded natural graphite of the porous matrix is pre-compressed before being set into place in the container. ### Claim 22 A structure for storing gas by absorption or adsorption, adapted so as to be positioned in a container, the structure including a gas storage element for storing gas by absorption or adsorption, wherein the structure further includes a compressible element maintained in contact with the gas storage element and adapted so as to deform under an action of forces exerted by the gas storage element during volume variations of the gas storage element during phases for storing and discharging gas, said compression element compressing in a direction corresponding to a direction of said action of forces; an alternation of layers including a layer of the gas storage element and at least one layer of the compressible element; wherein each layer of the gas storage element forms a rigid wafer or disc, and wherein the compressible element includes a metal plate. ### Claim 23 A method for filling a gas storage unit including a container including at least one gas storage element and at least one compressible element which includes a metal plate, wherein the method includes the following steps: placing in said container the at least one gas storage element, essentially without any gas, placing into said container, adjacent to the at least one gas storage element, the at least one compressible element, wherein the at least one compressible element is adapted to deform under an action of forces exerted by the at least one gas storage element during volume variations of the at least one gas storage element during phases for storing and discharging gas, so as to limit forces applied on the container by said at least one compressible element compressing in a direction corresponding to a direction of said action of forces, closing the container and applying to the container a source of pressurized gas, in order to store the gas by adsorption in each of the at least one gas storage elements, the at least one compressible element being adapted so as to deform under the action of forces exerted thereon because of volume variations of the at least one gas storage element during storing of the gas, so as to limit forces applied on the container; forming an alternation of layers including a layer of the at least one gas storage element and at least one layer of the at least one compressible element, wherein each layer of the at least one gas storage element forms a rigid wafer or disc. ### Claim 24 (depends on 23) The method according to claim 23, wherein the at least one gas storage element is a layer of powdery salt, the method including introducing the powdery salt into the container so as to form a layer and shaping of said layer by a plunger. ### Claim 25 A method for obtaining a structure for storing gas by absorption or adsorption, said structure including a container including a gas storage element, wherein the storage unit further includes a compressible element which includes a metal plate adapted to deform under an action of forces exerted by the storage element during volume variations of the gas storage element during phases for storing and discharging gas by said compressible element compressing in a direction corresponding to a direction of said action of forces, the method including the steps: depositing a gas storage element layer including a non-compressed or pre-compressed salt, depositing a layer of said compressible element, both steps of depositing being repeated so as to form a structure including an alternation of gas storage element layers and at least one intercalary compressible element layer, wherein the gas storage element layer and the compressible element layer are pre-assembled, both layers then being deposited in the container simultaneously; wherein each layer of the gas storage element forms a rigid wafer or disc. ### Claim 26 (depends on 25) The method according to claim 25, wherein pre-assembling is achieved by adhesive bonding and/or compressing the gas storage element layer and the layer of the compressible element against each other. ### Claim 27 A storage unit for storing gas by absorption or adsorption comprising: a container including a gas storage element; a compressible element disposed within the container and maintained in contact with the gas storage element, the compressible element adapted to deform under an action of forces exerted by the gas storage element during volume variations of the gas storage element during phases for storing and discharging gas so as to limit forces applied on the container by said compressible element by compressing in a direction corresponding to a direction of said action of forces; air alternation of layers including a layer of the gas storage element and at least one layer of the compressible element; wherein each layer of the gas storage element forms a rigid wafer or disc, wherein a height of a whole of the layers of the gas storage element is between 25% and 75% of a height of a whole of the at least one layer of the compressible element. ### Claim 28 (depends on 27) The storage unit according to claim 27, wherein a height of a whole of the layers of the gas storage element is between 50% and 75% of a height of a whole of the at least one layer of the compressible element. ### Claim 29 (depends on 27) The storage unit according to claim 27, wherein a height of each layer of the gas storage element is between 25% and 75% of a height of each of the at least one layer of the compressible element. ### Claim 30 (depends on 29) The storage unit according to claim 29, wherein a height of each layer of the gas storage element is between 50% and 75% of a height of each of the at least one layer of the compressible element. ### Claim 31 A storage unit for storing gas by absorption or adsorption comprising: a container including a gas storage element; a compressible element disposed within the container and maintained in contact with the gas storage element, the compressible element adapted to deform under an action of forces exerted by the gas storage element during volume variations of the gas storage element during phases for storing and discharging gas, so as to limit forces applied on the container by said compressible element by compressing in a direction corresponding to a direction of said action of forces; an alternation of layers including a layer of the gas storage element and at least one layer of the compressible element; wherein each layer of the gas storage element forms a rigid wafer or disc, wherein a volume of an assembly of gas storage elements is between 25% and 75% of a volume of an assembly of compressible elements. ### Claim 32 (depends on 31) The storage unit according to claim 31, wherein a volume of an assembly of gas storage elements is between 50% and 75% of a volume of an assembly of compressible elements. ### Claim 33 A storage unit for storing gas by absorption or adsorption comprising: a container including a gas storage element; a compressible element disposed within the container and maintained in contact with the gas storage element, the compressible element adapted to deform under an action of forces exerted by the gas storage element during volume variations of the gas storage element during phases for storing and discharging gas, so as to limit forces applied on the container by said compressible element by compressing in a direction corresponding to a direction of said action of forces; an alternation of layers including a layer of the gas storage element and at least one layer of the compressible element; wherein each layer of the gas storage element forms a rigid wafer or disc, wherein for each layer of the gas storage element and the at least one layer of the compressible element, a gas storage element volume is between 25% and 75% of a compressible element volume. ### Claim 34 (depends on 33) The storage unit according to claim 33, wherein for each layer of the gas storage element and the at least one layer of the compressible element, a gas storage element volume is between 50% and 75% of a compressible element volume.